214638-67-2Relevant academic research and scientific papers
A comparison of the rates of alkyl migration in the complexes (M = Fe, Ru, Os; Cp = η5-C5H5)
George, Robyn,Andersen, Jo-Ann M.,Moss, John R.
, p. 131 - 134 (2007/10/03)
The rates of alkyl migration for selected members of the series (M = Fe, Ru, Os; Cp = η5-C5H5; R = CH3 to n-C18H37) show dependence on both the alkyl group and the metal.Keywords: Iron; Ruthenium; Osmium; Cyclopentadienyl; Alkyl migration; Carbonyl
Alkylation and aldol reactions of iron acyl enolates
Liebeskind, Lanny S.,Welker, Mark E.
, p. 194 - 195 (2008/10/08)
Treatment of the acyliron complex CpFe-(CO)(PPh3)COCH3 with lithium diisopropylamide at low temperature in THF generates the corresponding enolate. Reaction of this enolate with alkyl halides gives high yields of C-alkylation product
