214898-33-6Relevant academic research and scientific papers
Binuclear silver(I) complexes with polydentate phosphine ligands 2-(diphenylphosphino)-6-pyridine and 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine
Kuang, Shan-Ming,Zhang, Zheng-Zhi,Wang, Qi-Guang,Mak, Thomas C. W.
, p. 2927 - 2930 (2007/10/03)
The new polydentate, pyridine-based phosphine ligand 2-(diphenylphosphino)-6-pyridine (L2) has been synthesized.The reaction of L2 with resulted in the formation of the binuclear silver(I) complex 2)2(ClO4)2>, which is stabilized by significant ?-? stacking interactions between its inter-ligand pyridyl fragments.In contrast, the reaction of 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine (L1) with gave the binuclear complex 1)2(MeCN)2>2, which exhibits a weak metal-metal interaction.
