2156-69-6Relevant articles and documents
Reactivity of Ph3PNLi towards PIII and PV electrophiles
Rahier, Nicolas J.,Volle, Jean-No?l,Lacour, Marie Agnès,Taillefer, Marc
, p. 6645 - 6650 (2008/12/20)
A study of the reactivity of Ph3P{double bond, long}NLi towards phosphorus electrophiles allowed us to develop a general method to isolate, or cleanly generate in situ, a broad family of polyphosphinimines displaying P{double bond, long}N-P bon
NEW SYNTHETIC APPLICATIONS OF METALLATED YLIDS
Cristau, Henri-Jean,Perraud, Anne,Manginot, Eric,Torreilles, Eliane
, p. 7 - 10 (2007/10/02)
The reaction of diylids 1 toward carbonates, carbamates, thiocarbamates, isocyanates, carbodiimides and sulfinates allow the quantitative preparation of functional Wittig reagents, which can be used in situ in the E-stereoselective synthesis of the corresponding α,β-unsaturated derivatives of carboxylic (or sulfinic) acids. The diylids 2 or yldiid 3 can be used as synthetic equivalents of RNH2- or NH2- anions and allow normal or functional alkylation of the nitrogen atom.
Chemical and structural characterization of W(CO)5OPPh2NPPh3. A novel complex containing a phosphine oxide ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation
Darensbourg, Donald J.,Pala, Magdalena,Simmons, Debra,Rheingold, Arnold L.
, p. 3537 - 3541 (2008/10/08)
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