2157-18-8

Basic information

• Product Name: 2-cyclohexyl-
• CAS NO: 2157-18-8
• Molecular Weight: 124.226
• Mol File: 2157-18-8.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 2-cyclohexyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-cyclohexyl-(2157-18-8)
• EPA Substance Registry System: 2-cyclohexyl-(2157-18-8)

Safety Data

• Hazardous Substances Data: 2157-18-8(Hazardous Substances Data)

Upstream product

• 2065-66-9 methyl-triphenylphosphonium iodide 
• 823-76-7 Cyclohexyl methyl ketone 
• 696-29-7 (1-methylethyl)-cyclohexane 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 13291-18-4 isopropenylmagnesium bromide 
• 4837-38-1 cyclohexanesulfonyl chloride 
• 931-48-6 2-cyclohexylacetylene 
• 75-24-1 trimethylaluminum 
• 16664-07-6 2-cyclohexyl-2-propanol 
• 7553-56-2 iodine 
• 142729-71-3 Carbonic acid 1-isopropenyl-cyclohexyl ester methyl ester 
• 931-51-1 cyclohexylmagnesiumchloride 
• 17729-74-7 1-(diphenylphosphino)propan-2-one 
• 78-95-5 chloroacetone 

Downstream Products

• 3908-31-4 1-Isopropenyl-1-cyclohexanol 
• 7697-55-4 2-cyclohexylprop-2-en-1-ol 
• 7697-61-2 2-cyclohexylacrylaldehyde 
• 1262985-48-7 2-(2-cyclohexylpropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1356012-61-7 (2,2-dibromo-1-methylcyclopropyl)cyclohexane 
• 1356012-19-5 (E)-3-(3-cyclohexylbut-1-en-1-yl)-1H-indole 
• 1356012-36-6 3,3'-(3-cyclohexylbutane-1,1-diyl)bis(1H-indole) 
• 1356012-71-9 (1-methylcycloprop-2-en-1-yl)cyclohexane 
• 1356012-62-8 (2-bromo-1-methylcyclopropyl)cyclohexane 
• 5442-00-2 2-cyclohexylpropan-1-ol 
• 1610962-54-3 (E)-5-cyclohexyl-3-methylhex-3-enoate 
• 1610962-55-4 (E)-5-cyclohexyl-3-methylhex-3-enol 
• 18594-05-3 4-cyclohexylacetophenone 

Relevant articles and documents

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METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method includes the steps of: (A) providing a compound (I) with an unsaturated double bond, a trifluoromethyl-containing reagent, and a catalyst; wherein, the catalyst is represented by Formula (II): M(O)mL1yL2z??(II);wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and(B) mixing the compound with an unsaturated double bond and the trifluoromethyl-containing reagent to perform an oxidative cleavage of the compound with the unsaturated double bond by using the catalyst in air or under oxygen atmosphere condition to obtain a compound represented by Formula (III):

METHOD FOR OXIDATIVE CLEAVAGE OF COMPOUNDS WITH UNSATURATED DOUBLE BOND

A method for oxidative cleavage of a compound with an unsaturated double bond is provided. The method comprises the following step: (A) providing a compound (I) with an unsaturated double bond, a reagent with trifluoromethyl, and a catalyst; wherein the catalyst is represented by the following formula (II): M(O)mL1yL2z (II); wherein, M, L1, L2, m, y, z, R1, R2 and R3 are defined in the specification; and (B) mixing the compound with an unsaturated double bond and the reagent with a trifluoromethyl to perform an oxidation of the compound with the unsaturated double bond by using the catalyst at air or an oxygen condition to get a compound presented as formula (III):

Enantioselective synthesis of cyclobutenes by intermolecular [2+2] cycloaddition with non-c2 symmetric digold catalysts

The enantioselective intermolecular gold-(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C2-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total synthesis of rumphellaone A.