216494-27-8

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 133604-03-2 ethyl (4S)-5-(((tert-butyldiphenyl)silyl)oxy)-4-methyl-2(E)-pentenoate 
• 95514-03-7 (R)-methyl 3-(tert-butyl(diphenyl)silyloxy)-2-methylpropanoate 
• 91751-24-5 (R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal 
• 127665-68-3 (4S)-5-(tert-butyldiphenylsilyloxy)-4-methyl-2-penten-1-ol 
• 127665-69-4 ((2R,3R)-3-((R)-1-((tert-butyldiphenylsilyl)oxy)propan-2-yl)oxiran-2-yl)methanol 

Downstream Products

• 216494-47-2 Acetic acid (2E,6E)-(1R,4R,5S,11R)-1-[(E)-(1R,2R)-1-(4-methoxy-benzyloxy)-2-methyl-hept-3-enyl]-4,11-dimethyl-10-methylene-13-(tetrahydro-pyran-2-yloxy)-5-(2-trimethylsilanyl-ethoxymethoxy)-trideca-2,6-dienyl ester 
• 216494-37-0 (4E,9E,13E)-(6R,7R,8R,11R,12S,18R)-7-(4-Methoxy-benzyloxy)-6,11,18-trimethyl-17-methylene-20-(tetrahydro-pyran-2-yloxy)-12-(2-trimethylsilanyl-ethoxymethoxy)-icosa-4,9,13-trien-8-ol 
• 216494-32-5 2-[(E)-(3R,9S,10R)-11-(tert-Butyl-diphenyl-silanyloxy)-3,10-dimethyl-4-methylene-9-(2-trimethylsilanyl-ethoxymethoxy)-undec-7-enyloxy]-tetrahydro-pyran 
• 216494-38-1 Acetic acid (2E,6E)-(1R,4R,5S,11R)-1-[(E)-(1R,2R)-1-(4-methoxy-benzyloxy)-2-methyl-hept-3-enyl]-4,11-dimethyl-10-methylene-13-oxo-5-(2-trimethylsilanyl-ethoxymethoxy)-trideca-2,6-dienyl ester 
• 216494-48-3 Acetic acid (2E,6E)-(1R,4R,5S,11R)-13-hydroxy-1-[(E)-(1R,2R)-1-(4-methoxy-benzyloxy)-2-methyl-hept-3-enyl]-4,11-dimethyl-10-methylene-5-(2-trimethylsilanyl-ethoxymethoxy)-trideca-2,6-dienyl ester 
• 216494-30-3 C₂₈H₄₃IO₃Si₂ 
• 216494-28-9 C₂₈H₄₂O₃Si₂ 
• 216494-43-8 (3R, 4R)-5-((tert-butyldiphenylsilyl)oxy)-4-methylpent-1-yn-3-ol 

Relevant academic research and scientific papers

Stereoselective synthesis of the C3-C15 fragment of callyspongiolide

The synthesis of C3-C15 fragment of callyspongiolide, a 14-membered macrolides isolated from the marine sponge Callyspongia sp., which was collected from the Indonesia, is reported. Highlights of the synthesis include construction of E-olefin through Juli