216689-47-3Relevant academic research and scientific papers
Stereoselective synthesis of (E)-chloroenynes or (E,E)-chlorodienes starting from a stereoisomeric mixture of 1,2-dichloroethylenes
Alami, Mouad,Peyrat, Jean-Fran?ois,Brion, Jean-Daniel
, p. 3007 - 3009 (2002)
Under palladium or nickel catalysis, a stereomeric mixture 1:1 of (Z) and (E)-1,2-dichloroethylene readily reacts with 1-alkynes, vinyl alanes or vinyl boranes to afford selectively the corresponding (E)-coupling product in good to excellent isolated yiel
Julia-Colonna asymmetric epoxidation reactions under non-aqueous conditions: Rapid, highly regio- and stereo-selective transformations using a cheap, recyclable catalyst
Allen, Joanne V.,Bergeron, Sophie,Griffiths, Matthew J.,Mukherjee, Shubhasish,Roberts, Stanley M.,Williamson, Natalie M.,Wu, L. Eduardo
, p. 3171 - 3179 (2007/10/03)
The asymmetric oxidation of some enones (Table 1), selected dienones 3-5, and a trienone 13 is accomplished using poly-L-leucine or poly-D-leucine and urea hydrogen peroxide under non-aqueous conditions. One of the resultant epoxy ketones 6 has been converted into the δ-lactones 19 and 22.
