2169-80-4

Basic information

• Product Name: phenyl 2,3,4,6-tetra-O-benzoyl β-D-glucopyranoside
• Synonyms: phenyl 2,3,4,6-tetra-O-benzoyl β-D-glucopyranoside
• CAS NO: 2169-80-4
• Molecular Weight: 672.688
• Mol File: 2169-80-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: phenyl 2,3,4,6-tetra-O-benzoyl β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2,3,4,6-tetra-O-benzoyl β-D-glucopyranoside(2169-80-4)
• EPA Substance Registry System: phenyl 2,3,4,6-tetra-O-benzoyl β-D-glucopyranoside(2169-80-4)

Safety Data

• Hazardous Substances Data: 2169-80-4(Hazardous Substances Data)

Upstream product

• 165877-99-6 2,3,4,6-tetra-O-Bz-β-D-glucopyranosyl bromide 
• 108-95-2 phenol 
• 98-88-4 benzoyl chloride 
• 1464-44-4 phenyl-β-D-glucopyranoside 

Downstream Products

• 39031-66-8 phenyl tetra-O-acetyl-α-L-idopyranoside 
• 76514-12-0 p-acetamidophenyl tetra-O-acetyl-α-D-idopyranoside 
• 76549-82-1 p-nitrophenyl tetra-O-acetyl-α-D-idopyranoside 

Relevant articles and documents

Stable Alkynyl Glycosyl Carbonates: Catalytic Anomeric Activation and Synthesis of a Tridecasaccharide Reminiscent of Mycobacterium tuberculosis Cell Wall Lipoarabinomannan

Oligosaccharide synthesis is still a challenging task despite the advent of modern glycosidation techniques. Herein, alkynyl glycosyl carbonates are shown to be stable glycosyl donors that can be activated catalytically by gold and silver salts at 25 °C in just 15 min to produce glycosides in excellent yields. Benzoyl glycosyl carbonate donors are solid compounds with a long shelf life. This operationally simple protocol was found to be highly efficient for the synthesis of nucleosides, amino acids, and phenolic and azido glycoconjugates. Repeated use of the carbonate glycosidation method enabled the highly convergent synthesis of tridecaarabinomannan in a rapid manner.