21710-99-6

Upstream product

• 1077-18-5 N-benzylidenebutan-1-amine 
• 57527-55-6 (E)-N-benzylidenebutan-1-amine 
• 100-52-7 benzaldehyde 
• 109-73-9 N-butylamine 

Downstream Products

• 50506-92-8 5-butylimino-2,4-diphenyl-[1,2,4]thiadiazolidine-3-thione 
• 50506-88-2 4-butyl-2-phenyl-5-phenylimino-[1,2,4]thiadiazolidine-3-thione 
• 50484-10-1 2-benzhydrylidene-3-butyl-5,5-diphenyl-oxazolidin-4-one 
• 2782-40-3 N-butylbenzamide 
• 28467-92-7 α-ethylcinnamaldehyde 

Relevant academic research and scientific papers

Atom economical synthesis of: N -alkylbenzamides via the iron(III) sulfate catalyzed rearrangement of 2-alkyl-3-aryloxaziridines in water and in the presence of a surfactant

A green and mild synthetic route to N-alkylbenzamides involves eco-friendly one pot synthesis of 2-alkyl-3-aryloxaziridines from N-alkylamines and benzaldehydes followed by iron(iii) sulfate catalyzed rearrangement to the corresponding amides in water as the solvent and in the presence of sodium dodecyl sulfate as the surfactant. This green approach affords N-alkylbenzamides in high overall yields under simple and minimum manipulation.

Synthesis of dihydrobenzisoxazoles by the [3 + 2] cycloaddition of arynes and oxaziridines

Dihydrobenzisoxazoles are readily prepared in good yields by the [3 + 2] cycloaddition of oxaziridines and arynes. The reaction involves an unusual cleavage of the C-O bond of the oxaziridine and tolerates a variety of substituents on the oxaziridine and the o-(trimethylsilyl)aryl triflate to form aryl-, heteroaryl-, alkyl-, and naphthyl-substituted dihydrobenzisoxazoles. The resulting halogen-substituted dihydrobenzisoxazoles are readily elaborated to more complex products using palladium-catalyzed crossing-coupling processes.

Chemo-enzymatic synthesis of N-alkyloxaziridines mediated by lipases and urea-hydrogen peroxide

Chemo-enzymatic oxidation of various N-alkylimines mediated by lipases produced the corresponding E- or a mixture of E- and Z-N-oxaziridines with moderate to very high yields (>99%) and good to excellent selectivities (70-100%) within 30 min to 6 h in var

Iron and manganese (III) - Porphyrins as new applicable catalysts for selective oxidation of imines with urea-hydrogen peroxide

A variety of imines were oxidised with urea-hydrogen peroxide using iron(III) and manganese (III)- tetraphenylporphyrins [Fe(TPP)Cl], [Mn(TPP)Cl] and manganese (III)-octabromotetraphenyl porphyrin [Mn(TPPBr8)Cl] as catalysts. Experimental resul