217964-65-3Relevant academic research and scientific papers
On 1,4-diastereoselectivity in the chiral allylsilane addition to chiral α-substituted aldehydes
Dias, Luiz C.,Giacomini, Rosana
, p. 5343 - 5346 (2007/10/03)
Chiral allyisilane 2 reacted with chiral α-substituted aldehydes to afford the corresponding 1,4-syn-products with good diastereoseletivities. The best selectivities are observe when the reactions are carried out by transmetallation of allylsilane using T
