218608-73-2

Upstream product

• 20440-94-2 N,N-bis(4-methoxyphenyl)aniline 
• 62-53-3 aniline 
• 106-40-1 4-bromo-aniline 
• 696-62-8 para-iodoanisole 
• 1440427-06-4 4-methoxy-N-(4-methoxyphenyl)-N-(4-((triethyllsilyl)ethynyl)phenyl)aniline 
• 90965-06-3 dimethyl 1-(1-diazo-2-oxopropyl)phosphonate 
• 89115-20-8 4-[bis(4-methoxyphenyl)amino]benzaldehyde 
• 540-38-5 p-Iodophenol 
• 194416-45-0 4-bromo-N,N-bis-(4-methoxyphenyl)aniline 
• 589-87-7 1,4-bromoiodobenzene 
• 16116-78-2 (4-bromophenyl)(trimethylsilyl)acetylene 
• 108-86-1 bromobenzene 
• 101-70-2 bis(4-methoxyphenyl)amine 
• 201802-15-5 N,N-bis(4-methoxyphenyl)-4'-iodophenylamine 

Downstream Products

• 908275-05-8 2-{4-[bis-(4-methoxyphenyl)amino]phenylethynyl}-5-trimethylsilanylethynylbenzonitrile 
• 1071780-69-2 dimethyl 2,3-bis(N,N-di-4-methoxyphenyl-4-aminophenylethynyl)fumarate 
• 1384935-41-4 N,N-di(4-methoxyphenyl)-N-[4-[2-(pyren-2-yl)ethynyl]phenyl]amine 
• 1384935-39-0 1-(pyren-2-yl)-2-(4-(N,N-bis-4-methoxyphenyl)amine)-3,4,5,6-(tetraphenyl)benzene 
• 1404492-11-0 4-{2-(4-(dimesitylboryl)phenyl)ethynyl}-N,N-di(4-methoxyphenyl)benzenamine 
• 1542226-79-8 Pt(C≡CC6H4N(C6H4OMe-4)2)2(PPh3)2 

Relevant academic research and scientific papers

Direct iodination of electron-deficient benzothiazoles: Rapid access to two-photon absorbing fluorophores with quadrupolar D-π-A-π-D architecture and tunable heteroaromatic core

Direct iodination of benzothiazoles under strong oxidative/acidic conditions leads to a mixture of iodinated heteroarenes with 1-2 major components, which are easily separable and which structures depend on the I2 equivalents used. Among the unexpected bu

Oxidative C-H Homocoupling of Push-Pull Benzothiazoles: An Atom-Economical Route to Highly Emissive Quadrupolar Arylamine-Functionalized 2,2′-Bibenzothiazoles with Enhanced Two-Photon Absorption

Copper(II)-catalyzed C-H/C-H coupling of dipolar 2-H-benzothiazoles end-capped with triphenylamine moieties affords highly fluorescent 2,2′-bibenzothiazoles with quadrupolar (D-π-A-π-D) architecture displaying large two-photon absorption (TPA) cross sections (543-1252 GM) in the near-infrared region. The notably higher TPA performance as compared to quadrupolar π-systems with a widely used 2,2′-bipyridine core, along with the ease of the synthesis and chelating N^N ability, makes the title biheteroaryl platform an attractive building block for a large scope of functional dyes exploiting nonlinear optical phenomena.

Dendritic-Like Molecules Built on a Pillar[5]arene Core as Hole Transporting Materials for Perovskite Solar Cells

Multi-branched molecules have recently demonstrated interesting behaviour as charge-transporting materials within the fields of perovskite solar cells (PSCs). For this reason, extended triarylamine dendrons have been grafted onto a pillar[5]arene core to generate dendrimer-like compounds, which have been used as hole-transporting materials (HTMs) for PSCs. The performances of the solar cells containing these novel compounds have been extensively investigated. Interestingly, a positive dendritic effect has been evidenced as the hole transporting properties are improved when going from the first to the second-generation compound. The stability of the devices based on the best performing pillar[5]arene material has been also evaluated in a high-throughput ageing setup for 500 h at high temperature. When compared to reference devices prepared from spiro-OMeTAD, the behaviour is similar. An analysis of the economic advantages arising from the use of the pillar[5]arene-based material revealed however that our pillar[5]arene-based material is cheaper than the reference.

Monocarbazole/dicarbazole hole transport material as well as preparation method and application thereof

The invention discloses a monocarbazole/dicarbazole hole transport material as well as a preparation method and application thereof. The chemical structural general formula of the monocarbazole/dicarbazole hole transport material is shown as a formula I.

Luminescence Tunable Europium and Samarium Complexes: Reversible On/Off Switching and White-Light Emission

Single-molecule functional materials with luminescence tunable by external stimuli are of increasing interest due to their application in sensors, display devices, biomarkers, and switches. Herein, new europium and samarium complexes with ligands having triphenylamine (TPA) groups as the redox center and 2,2′-bipyridine (bpy) as the coordinating groups and diketonate (tta) as the second ligand have been constructed. The complexes show white-light emission in selected solvents for proper mixtures of the emission from Ln3+ ions and the ligands. Meanwhile, they exhibit reversible luminescence switching on/off properties by controlling the external potential owing to intramolecular energy transfer from the Ln3+ ions to the electrochemically generated radical cation of TPA+. Time-dependent density functional theory (TD-DFT) calculations have been performed to study the electronic spectra. The proposed intramolecular energy transfer processes have been verified by density functional theory (DFT) studies.

Arylamino-fluorene derivatives: Optically induced electron transfer investigation, redox-controlled modulation of absorption and fluorescence

A series of biarylaminofluorene-based systems with donor-π-donor (D-π-D) structure have been designed and synthesized in order to study the dependence on the π-conjugated bridge length of the intervalence charge-transfer transitions (IV-CT) and of the electronic coupling between the redox centers. To this purpose cyclic voltammetry, UV/Vis-NIR, fluorescence spectroscopy and computational investigations have been carried out to characterize the electronic structure of the compounds in the neutral as well as in the mono- and dication states. Additionally, a study of related D-π compounds has been performed to elucidate the effect of the interaction between two redox centers. Interestingly it was observed that the mono- and dication species exhibit intense transition bands in the NIR region, in the 10000-15000 cm?1 range, whose intensity depends on the oxidation state and thus it can be reversibly tuned by an applied potential. In a similar way, all compounds show an oxidation state dependent fluorescence which leads to electrofluorochromism. Particularly significant is the mixed valence behavior that provides these systems singular optoelectronic properties, making them excellent active components for electrochromic and electrofluorochromic applications.

ORGANIC DYES, COMPOSITIONS AND DYE-SENSITIZED SOLAR CELL

The present invention relates to an organic dye having improved stability to heat, light and water, to a composition comprising the same, and to a dye-sensitized solar cell and, more specifically, to an organic dye represented by chemical formula 1, to a composition comprising the same, and to a dye-sensitized solar cell. The chemical formula 1 is the same as defined in claim 1.COPYRIGHT KIPO 2020

Influence of Donor-Substituents on Triphenylamine Chromophores Bearing Pyridine Fragments

Efficient synthetic routes that combine different palladium-catalyzed cross-coupling reactions have been developed for the preparation of a new family of push-pull derivatives in which pyridine was used as the acceptor group and different para-substituted diphenylamines as the donor groups. All compounds showed absorption in the UV/Vis region and blue-green emission with high quantum yields. Significant red shifts were observed in the absorption and fluorescence emission maxima on increasing the electron-donating ability of the substituents or on incorporating a π-conjugated linker. This finding can be explained on the basis of enhanced intramolecular charge transfer (ICT). Strong emission solvatochromism confirmed the formation of an intramolecular charge-separated emitting state. The HOMO-LUMO energy gaps have been estimated by experimental electrochemical measurements and the results were interpreted with the aid of DFT calculations. The thermal behavior of all materials has also been studied by differential scanning calorimetry.

Effect of alkyl chain length on the properties of triphenylamine-based hole transport materials and their performance in perovskite solar cells

A new series of diacetylide-triphenylamine (DATPA) derivatives with five different alkyl chains in the para position, MeO, EtO, nPrO, iPrO and BuO, were synthesised, fully characterised and their function as hole-transport materials in perovskite solar cells (PSC) studied. Their thermal, optical and electrochemical properties were investigated along with their molecular packing and charge transport properties to analyse the influence of different alkyl chains in the solar cell parameters. The shorter alkyl chain facilitates more compact packing structures which enhanced the hole mobilities and reduced recombination. This work suggests that the molecule with the methoxy substituent (MeO) exhibits the best semiconductive properties with a power conversion efficiency of up to 5.63%, an open circuit voltage (Voc) of 0.83 V, a photocurrent density (Jsc) of 10.84 mA cm-2 and a fill factor of 62.3% in perovskite solar cells. Upon replacing the methoxy group with longer alkyl chain substituents without changing the energy levels, there is a decrease in the charge mobility as well as PCE (e.g. 3.29% for BuO-DATPA). The alkyl chain length of semiconductive molecules plays an important role in achieving high performance perovskite solar cells.

Charge transfer emission in oligotriarylamine-triarylborane compounds

Donor-acceptor compounds exhibiting charge transfer emission are of interest in a variety of different contexts, for example, for nonlinear optical processes and for sensor applications. Recently investigated triarylamine-triarylborane compounds represent an important class of donor-acceptor systems, and we explored to what extent their charge-transfer properties can be further improved by using stronger amine donors and borane acceptors than prior studies. The oligotriarylamine employed here is a much stronger donor than previously used triarylamines containing single nitrogen centers. In order to increase the acceptor strength, the electron-accepting unit was equipped with two (instead of one) dimesitylboron substituents. In our comparative study, six donor-acceptor compounds were synthesized and investigated by cyclic voltammetry and optical spectroscopy. An increase of the donor strength through replacement of an ordinary triarylamine by an oligotriarylamine unit leads to the expected energetic stabilization of charge transfer (CT) excited states, but the emission solvatochromism is not more pronounced. The attempted increase of the acceptor strength by substitution of the acceptor moiety by two (instead of one) dimesitylboron groups leads to a drastic decrease of emission quantum yields. On the basis of these results, our purely experimental study provides fundamental guidelines for the design of new triarylamine-triarylborane donor-acceptor compounds with favorable charge-transfer emission properties.