219511-71-4Relevant articles and documents
Downsizing of enzymes by chemical methods: arginine mimics with low pk a values increase the rates of hydrolysis of RNA model compounds
Geiger, Lars,Schmuck, Carsten,Lindgren, N. Johan V.,Baltzer, Lars,Razkin, Jesus
, p. 6722 - 6725 (2009)
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Triazine-Based Janus G-C Nucleobase as a Building Block for Self-Assembly, Peptide Nucleic Acids, and Smart Polymers
Meena, Chhuttan L.,Singh, Dharmendra,Kizhakeetil, Bhavya,Prasad, Manasa,George, Malini,Tothadi, Srinu,Sanjayan, Gangadhar J.
, p. 3186 - 3195 (2021/02/16)
This communication reports on the utility of a triazine-based self-assembling system, reminiscent of a Janus G-C nucleobase, as a building block for developing (1) supramolecular polymers, (2) peptide nucleic acids (PNAs), and (3) smart polymers. The strategically positioned self-complementary triple H-bonding arrays DDA and AAD facilitate efficient self-assembly, leading to a linear supramolecular polymer.
Supramolecular Self-Sorting Networks using Hydrogen-Bonding Motifs
Coubrough, Heather M.,van der Lubbe, Stephanie C. C.,Hetherington, Kristina,Minard, Aisling,Pask, Christopher,Howard, Mark J.,Fonseca Guerra, Célia,Wilson, Andrew J.
supporting information, p. 785 - 795 (2019/01/04)
A current objective in supramolecular chemistry is to mimic the transitions between complex self-sorted systems that represent a hallmark of regulatory function in nature. In this work, a self-sorting network, comprising linear hydrogen motifs, was created. Selecting six hydrogen-bonding motifs capable of both high-fidelity and promiscuous molecular recognition gave rise to a complex self-sorting system, which included motifs capable of both narcissistic and social self-sorting. Examination of the interactions between individual components, experimentally and computationally, provided a rationale for the product distribution during each phase of a cascade. This reasoning holds through up to five sequential additions of six building blocks, resulting in the construction of a biomimetic network in which the presence or absence of different components provides multiple unique pathways to distinct self-sorted configurations.
