21983-00-6Relevant academic research and scientific papers
PROCESS FOR PREPARING BORONIC ACIDS AND ESTERS IN THE PRESENCE OF MAGNESIUM METAL
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Page/Page column 9-10, (2011/11/30)
The present invention relates to the process for preparing a boronic acid or ester chemically, in which an aromatic compound is reacted with a boronating agent, in the presence of magnesium metal (Mg0). The invention also relates to the boronic acids or esters that can be obtained by means of this process and to the use thereof for example as a synthesis intermediate, in the Suzuki reaction, in the pharmaceutical or alternatively electronics field.
Electrosynthesis of benzylboronic acids and esters
Pintaric,Laza,Olivero,Du?ach
, p. 8031 - 8033 (2007/10/03)
A novel preparation of benzylboronic acids and esters is described by using an electrochemical reductive coupling reaction between benzylic halides and borating agents (trialkylborates or pinacolborane). The reaction is carried out at room temperature in DMF or THF with the use of a sacrificial magnesium anode in a single-compartment cell.
