220155-65-7Relevant academic research and scientific papers
Stereoselective sulfoxidation of α-mannopyranosyl thioglycosides: The exo-anomeric effect in action
Crich, David,Mataka, Jan,Sun, Sanxing,Lam,Rheingold, Arnold L.,Wink, Donald J.
, p. 2763 - 2764 (1998)
As a consequence of the exo-anomeric effect, and in contrast to their β-anomers, α-thioglycosides undergo stereoselective oxidation to give very predominantly the R-sulfoxides, as revealed by X-ray crystallography.
