Chemical Communications p. 2763 - 2764 (1998)
Update date:2022-08-04
Topics:
Crich, David
Mataka, Jan
Sun, Sanxing
Lam
Rheingold, Arnold L.
Wink, Donald J.
As a consequence of the exo-anomeric effect, and in contrast to their β-anomers, α-thioglycosides undergo stereoselective oxidation to give very predominantly the R-sulfoxides, as revealed by X-ray crystallography.
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