220384-55-4Relevant articles and documents
An expedient reductive method for conversion of ketoximes to the corresponding carbonyl compounds
Majireck, Max M.,Witek, Jason A.,Weinreb, Steven M.
experimental part, p. 3555 - 3557 (2010/08/07)
A wide array of readily prepared pivalates of ketoximes can be converted to the corresponding ketones in good yields by treatment with iron powder in THF containing catalytic amounts of both trimethylsilyl chloride and glacial acetic acid at room temperature for 30 min, followed by a brief aqueous workup.
Regioselective palladium-catalyzed formate reduction of N-heterocyclic allylic acetates
Cheng, Hsiu-Yi,Sun, Chong-Si,Hou, Duen-Ren
, p. 2674 - 2677 (2007/10/03)
The regioselective palladium-catalyzed formate reduction of allylic acetates in five- to eight-membered heterocycles is reported. Reduction of allylic acetates under mild conditions using allylpalladium chloride dimer, phosphines, and formic acid/triethyl
New synthesis of SKF 89976A
Chang, Meng-Yang,Wang, Si-Yun,Pai, Chun-Li
, p. 6389 - 6392 (2007/10/03)
Substituted 4,4-diaryl-3-butenyl-1-amines are synthesized in nearly 34-47% overall yields starting from 3-hydroxypiperidine by the regioselective Baeyer-Villiger lactonization, Grignard addition and elimination sequence. This facile strategy was also used