22040-31-9Relevant academic research and scientific papers
Enantiopure C1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation
Monfette, Sebastien,Turner, Zoe R.,Semproni, Scott P.,Chirik, Paul J.
, p. 4561 - 4564 (2012/04/23)
Enantiopure C1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.
The positional and structural izomerization equilibrium of branched pentylbenzenes
Naumkin,Nesterova,Nesterov,Vodenkova,Golovin
, p. 141 - 148 (2011/08/05)
The equilibrium of the positional and structural isomerization of branched monopentylbenzenes, pentyltoluenes, and pentyl-o-xylenes was studied. It was found that the 1,2-dimethylpropyl substituted derivatives prevail over the 1,1-dimethylpropyl substituted isomers in the equilibrium mixture of all of the examined groups of compounds. The thermodynamic characteristics of the structural isomerization of pentylbenzenes were calculated from the experimental data.
