2206-89-5

Basic information

• Product Name: 2-CHLOROETHYL ACRYLATE
• Synonyms: 2-CHLOROETHYL ACRYLATE;Acrylic acid-β-chloroethyl ester;BETA-CHLOROETHYL ACRYLATE;B-CHLOROETHYL ACRYLATE;2-Chlorethylester kyseliny akrylove;2-chlorethylesterkyselinyakrylove;2-Chloroethyl ester of acrylic acid;2-propenoicacid,2-chloroethylester
• CAS NO: 2206-89-5
• Molecular Formula: C₅H₇ClO₂
• Molecular Weight: 134.56
• EINECS: 218-619-1
• Product Categories: monomer
• Mol File: 2206-89-5.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 64-66°C 20mm
• Flash Point: 59℃
• Appearance: /
• Density: 1.125 g/mL at 25 °C
• Vapor Pressure: 1.53mmHg at 25°C
• Refractive Index: n20/D1.125
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2-CHLOROETHYL ACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-CHLOROETHYL ACRYLATE(2206-89-5)
• EPA Substance Registry System: 2-CHLOROETHYL ACRYLATE(2206-89-5)

Safety Data

• Hazard Codes: T,N
• Statements: 36/37/38-50-36-25-10
• Safety Statements: 26-36/37/39-61-45
• RIDADR: UN 1992 6.1(3) / PGIII
• WGK Germany: 3
• RTECS: AS6300000
• Hazardous Substances Data: 2206-89-5(Hazardous Substances Data)

Usage

General Description

Insoluble in water (<1 mg/mL at 70°F) .

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

2-CHLOROETHYL ACRYLATE may be sensitive to light and heat .

Fire Hazard

Flash point data for 2-CHLOROETHYL ACRYLATE are not available, but 2-CHLOROETHYL ACRYLATE is probably combustible.

InChI:InChI=1/C5H7ClO2/c1-2-5(7)8-4-3-6/h2H,1,3-4H2

Upstream product

• 57-57-8 β-Propiolactone 
• 107-07-3 2-chloro-ethanol 
• 62899-33-6 O-acetyl-lactic acid-(2-chloro-ethyl ester) 
• 292638-85-8 acrylic acid methyl ester 
• 814-68-6 acryloyl chloride 
• 79-10-7 acrylic acid 

Downstream Products

• 40220-08-4 tris-<2-(2-propenoic acid) ethyl ester> isocyanuric acid ester 
• 15458-78-3 2-(1,3-dioxoisoindolin-2-yl)ethyl acrylate 
• 139883-15-1 3-phenyl-3-hydroxy-2-methylene-propanoic acid 2-chloroethyl ester 
• 4513-56-8 2-bromoethyl methacrylate 

Relevant articles and documents

Applications of pH sensor using a covalent bond indicator based on containing functional group copolymer

The purpose of this study was to immobilize copolymer that is able to covalent bonding with pH indicator. The pH sensitive polymers were synthesized with copolymers that are consisted of acryloylamino acid and chloroalkyl acrylate with MMA to get the optical fiber matrix. Fluoresceinamine indicator, containing amino group was immobilized covalently on prepared copolymers. The prepared pH sensing copolymers were measured sensitivity by UV-Visible spectroscopy. The pH-dependent value of copolymers was examined in the pH range of 2.00 ~ 12.00 HCl/NaOH solution at room temperature. As the length side chain and MMA molar ratio of the copolymers increases, the intensity decreases. Compared with imine group of copolymer-dye derivatives, amide group derivatives have a bathochromic shift on the UV-Visible spectrum.

Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors

Alkyl chlorides are common functional groups in synthetic organic chemistry. However, the engagement of unactivated alkyl chlorides, especially tertiary alkyl chlorides, in transition-metal-catalyzed C-C bond formation remains challenging. Herein, we describe the development of a TiIII-catalyzed radical addition of 2° and 3° alkyl chlorides to electron-deficient alkenes. Mechanistic data are consistent with inner-sphere activation of the C-Cl bond featuring TiIII-mediated Cl atom abstraction. Evidence suggests that the active TiIII catalyst is generated from the TiIV precursor in a Lewis-acid-assisted electron transfer process.

Synthesis of acyloxyalkyl esters of thiocarbonic and dithiocarbamic acids

Reactions of acyloxyalkyl chloride with alkaline salts of alkylxanthic, butyltrithiocarbonic, and diethyldithiocarbamic acids afforded a series of acyloxyalkyl esters of various nature and positions of the acyl groups in the molecule.