220645-11-4Relevant academic research and scientific papers
One-pot synthesis of cyclic oligosaccharides by the polyglycosylation of monothioglycosides
Someya, Hidehisa,Seki, Takehito,Ishigami, Gota,Itoh, Taiki,Saga, Yutaka,Yamada, Yasuyuki,Aoki, Shin
, (2019/12/14)
Cyclic oligosaccharides such as cyclodextrins (CyDs) have been known as excellent host molecules for the inclusion of various organic guest molecules. The development of new synthetic methods for preparing cyclic oligosaccharides from simple and readily a
An efficient and recyclable catalyst for the cleavage of tert-butyldiphenylsilyl ethers
Yan, Shiqiang,Ding, Ning,Zhang, Wei,Wang, Peng,Li, Yingxia,Li, Ming
, p. 6 - 20 (2012/07/13)
An efficient, chemoselective, and environment-friendly method for the deprotection of tert-butyldiphenylsilyl ethers mediated by triflic acid supported on silica gel is reported. A wide range of tert-butyldiphenylsilyl ethers derived from carbohydrate and saponin residues can be smoothly cleaved in the presence of various types of other protecting groups in good to excellent yields in acetonitrile. This heterogeneous reaction does not require aqueous workup, and the supported catalyst can be readily recycled.
Programmable one-pot oligosaccharide synthesis
Zhang, Zhiyuan,Ollmann, Ian R.,Ye, Xin-Shan,Wischnat, Ralf,Baasov, Timor,Wong, Chi-Huey
, p. 734 - 753 (2007/10/03)
In an effort to develop a broadly applicable approach to the facile one- pot synthesis of oligosaccharides, the reactivity of a number of p- methylphenyl thioglycoside (STol) donors which are either fully protected or have one hydroxyl group exposed has b
