22089-76-5Relevant academic research and scientific papers
Methyltrioxorhenium catalyzed oxidation of 1,2-diols to 1,2-diketones using hydrogen peroxide as oxidant
Jain, Suman L.,Sharma, Vishal B.,Sain, Bir
, p. 1233 - 1235 (2004)
A variety of 1,2-diols were oxidized selectively to the corresponding 1,2-diketones by the dropwise addition of 30% aqueous hydrogen peroxide using methyltrioxorhenium as catalyst.
Highly efficient and selective oxidation of secondary alcohols to ketones under organic solvent and transition metal free conditions
Jain, Suman L.,Sharma, Vishal B.,Sain, Bir
, p. 6841 - 6847 (2007/10/03)
The aqueous HBr/H2O2 was found to be highly efficient and green catalytic system for the selective oxidation of the secondary alcohols to ketones in excellent yields under organic solvent free conditions. The results of the oxidation of the secondary alcohols with solid alternatives of the aqueous hydrogen peroxide like SPC or SPB are also described.
A new and efficient transition metal-free oxidation of secondary alcohols to ketones using aqueous HBr and H2O2
Sharma, Vishal B.,Jain, Suman L.,Sain, Bir
, p. 173 - 175 (2007/10/03)
Aqueous HBr/H2O2 was found to be an efficient and green system for the oxidation of secondary alcohols in excellent yields under very mild conditions.
Ruthenium catalyzed oxidation of 1,2-diols to 1,2-diketones using bromamine-T as an oxidizing agent
Jain, Suman L.,Sharma, Vishal B.,Sain, Bir
, p. 465 - 469 (2007/10/03)
A variety of 1,2-diols were selectively oxidized to their corresponding 1,2-diketones with bromamine-T using RuCl3 · xH2O as catalyst in alkaline acetonitrile/ water (1:1) medium. The reaction was pH dependent (pH 8.4), and at higher pH the rate of the reaction decreased significantly. Copyright Taylor & Francis, Inc.
Cobalt phthalocyanine catalyzed aerobic oxidation of secondary alcohols: An efficient and simple synthesis of ketones
Sharma, Vishal B.,Jain, Suman L.,Sain, Bir
, p. 383 - 386 (2007/10/03)
A variety of activated and non-activated secondary alcohols have been efficiently oxidized to their corresponding ketones in excellent yields with molecular oxygen using cobalt phthalocyanine as catalyst in the presence of powdered potassium hydroxide.
