14,15-Octacosanedione

Base Information

• Chemical Name: 14,15-Octacosanedione
• CAS No.: 22089-76-5
• Molecular Formula: C28H54O2
• Mol file: 22089-76-5.mol

Synonyms:

Chemical Property of 14,15-Octacosanedione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 14,15-Octacosanedione

There total 5 articles about 14,15-Octacosanedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

15-hydroxy-octacosan-14-one (5632-98-4) → 14,15-octacosanedione (22089-76-5)

Guidance literature:

With hydrogen bromide; dihydrogen peroxide; at 80 ℃; for 2.5h;

DOI:10.1016/j.tet.2006.04.097

Reference yield: 80.0%

octacosane-14,15-diol (671207-27-5) → 14,15-octacosanedione (22089-76-5)

Guidance literature:

With ruthenium trichloride; bromamine T; In water; acetonitrile; at 80 ℃; for 0.916667h; pH=8.4;

DOI:10.1081/SCC-200048974

Reference yield:

methyl myristoate (124-10-7) → 14,15-octacosanedione (22089-76-5)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium; xylene / 105 °C

2: FeCl₃; glacial acetic acid / 100 - 110 °C

With sodium; iron(III) chloride; acetic acid; xylene;

upstream raw materials:

15-hydroxy-octacosan-14-one

oxalyl dichloride

dodecylmalonic acid

octacosane-14,15-diol

Refernces

• 1、 Jain, Suman L.,Sharma, Vishal B.,Sain, Bir. "Highly efficient and selective oxidation of secondary alcohols to ketones under organic solvent and transition metal free conditions". . p. 6841 - 6847. Retrieved 2007/10/03.
• 2、 Jain, Suman L.,Sharma, Vishal B.,Sain, Bir. "Ruthenium catalyzed oxidation of 1,2-diols to 1,2-diketones using bromamine-T as an oxidizing agent". . p. 465 - 469. Retrieved 2007/10/03.