221362-60-3

Upstream product

• 917029-05-1 methyl (S(P))-(o-hydroxyphenyl)(phenyl)phosphinite-P-borane 
• 74-88-4 methyl iodide 
• 95-56-7 2-hydroxybromobenzene 
• 221277-86-7 N,N-diethyl-1-(2-methoxyphenyl)-1-phenylphosphinamine 
• 67-56-1 methanol 
• 13292-87-0 dimethyl sulfide borane 

Downstream Products

• 499120-28-4 ferrocenyl-2-methoxyphenylphenylphosphine borane 
• 190907-17-6 (l)+(u)-1,1'-bis(2-methoxyphenyl(phenyl)phosphino)ferrocene borane 
• 221362-61-4 (R,S)-1,1'-bis(2-methoxyphenyl(phenyl)phosphino)ferroceneborane 

Relevant academic research and scientific papers

Asymmetric synthesis of SMS-Phos series' precursor and a naphthalene analogue

An efficient and high-yielding (up to 57% overall yield) asymmetric route to enantiopure P-stereogenic 1,2-bis[(o-hydroxyaryl)(phenyl)phosphino-P-borane] ethanes wherein aryl = phenyl and naphthyl, is presented. The occurring P-stereomutation is confirmed

Ferrocenyl diphosphines containing stereogenic phosphorus atoms. Synthesis and application in the rhodium-catalyzed asymmetric hydrogenation

Enantiomerically pure (R)-2-methoxyphenyl(phenyl)-O-methylphosphinite borane (1a) and CR)-1-naphthyl(phenyl)-O-methylphosphinite borane (1b) react with 1,1′-dilithioferrocene to give (S,S)-1,1′-bis(2-methoxyphenyl(phenyl)phosphino)ferrocene borane (2a) an