222057-25-2

Upstream product

• 100-39-0 benzyl bromide 
• 849465-30-1 octyl 6-O-triphenylmethyl-α-D-mannopyranoside 
• 950602-63-8 octyl 6-O-(tert-butyldiphenylsilyl)-α-D-mannopyranoside 
• 849465-31-2 octyl 2,3,4-tri-O-benzyl-6-O-triphenylmethyl-α-D-mannopyranoside 
• 124650-29-9 octyl α-D-mannopyranoside 

Downstream Products

• 849465-39-0 octyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849465-37-8 octyl 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 950602-64-9 octyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 1207163-11-8 octyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 1207163-24-3 octyl 2-O-acetyl-3,4-O-isopropylidene-6-O-(tert-butyldiphenylsilyl)-α-D-mannopyranosyl-(1->6)-2,3,4,-tri-O-benzyl-α-D-talopyranoside 
• 849208-13-5 octyl 3,4-di-O-benzyl-6-O-tert-butyldiphenylsilyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849208-15-7 octyl 3,4-di-O-benzyl-6-deoxy-2-O-methyl-6-phthalimido-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849208-14-6 octyl 3,4-di-O-benzyl-2-O-methyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849208-12-4 octyl 3,4-di-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849208-18-0 octyl 3,4-di-O-benzyl-6-deoxy-6-fluoro-2-O-methyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849208-16-8 octyl 3,6-anhydro-4-O-benzyl-2-O-methyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849465-35-6 octyl 3,4,6-tri-O-benzyl-2-O-(methylthio)thiocarbonyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849465-33-4 octyl 3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 849465-34-5 octyl 2-O-methyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

Novel synthetic (1 → 6)-α-d-mannodisaccharide substrates support processive mannosylation catalysed by the mycobacterial cell envelope enzyme fraction

Three new (1 → 6)-α-d-mannodisaccharides with cyclohexylalkyl or octylsulfonyl function like aglycone were synthesized and screened in the mycobacterial mannosyltransferase assay. 2-Cyclohexylethyl (1 → 6)-α-d-Man2 acted as the best acceptor substrate, wh

Synthesis of deoxy and methoxy analogs of octyl α-d-mannopyranosyl-(1→6)-α-d-mannopyranoside as probes for mycobacterial lipoarabinomannan biosynthesis

A panel of analogs of the disaccharide α-d-Manp-(1→6)-α-d-Manp-OOctyl, a known acceptor substrate for a polyprenol monophosphomannose-dependent α-(1→6)-mannosyltransferase involved in the assembly of the α-(1→6)-linked mannan core of mycobacterial lipoara

Modified mannose disaccharides as substrates and inhibitors of a polyprenol monophosphomannose-dependent α-(1→6)-mannosyltransferase involved in mycobacterial lipoarabinomannan biosynthesis

A panel of α-(1→6)-linked mannose disaccharides (5-8) in which the 2′-OH group has been replaced, independently, by deoxy, fluoro, amino, and methoxy functionalities has been synthesized. Evaluation of these compounds as potential substrates or inhibitors

Iodine and its interhalogen compounds: Versatile reagents in carbohydrate chemistry IX. A mild and selective deprotection of tert- butyldimethylsilyl (TBDMS) ethers in the presence of various protecting groups using iodine monobromide

Treatment of O-tert-butyldimethylsilyl (TBDMS) ethers of simple alcohols, carbohydrates or nucleosides with iodine monobromide in methanol or acetonitrile constitutes an effective method for their facile deprotection. The method can tolerate acid labile functionalities such as acetals, O-p- methoxybenzyl ethers, etc. as well as base labile groups such as esters and amides. An O-tert-butyldiphenylsilyl ether also survives the reaction conditions.