222844-98-6

Upstream product

• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 824-94-2 p-methoxybenzyl chloride 
• 100-39-0 benzyl bromide 
• 1450734-54-9 4-methoxybenzyl N-phenyl-2,2,2-trifluoroacetimidate 
• 105-13-5 4-Methoxybenzyl alcohol 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 37073-70-4 1-(6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-trityloxyethanol 
• 1380315-47-8 3-O-benzyl-5-O-(4-methoxybenzyl)-6-O-triphenylmethyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 

Downstream Products

• 1380315-48-9 3-O-benzyl-6-O-(2-bromomethylbenzyl)-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 1380315-49-0 6-O-(2-azidomethylbenzyl)-3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 1380315-50-3 C₆₈H₇₃N₃O₁₂S 
• 1380315-51-4 C₆₀H₆₅N₃O₁₁S 
• 1380315-53-6 6-O-(3-azidomethylbenzyl)-3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 1380315-54-7 C₆₈H₇₃N₃O₁₂S 
• 1380315-55-8 C₆₀H₆₅N₃O₁₁S 
• 1380315-52-5 3-O-benzyl-6-O-(3-bromomethylbenzyl)-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 198995-06-1 (S)-2-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-(4-methoxy-benzyloxy)-ethanethiol 
• 83318-92-7 ethyl p-methoxybenzyl sulfide 

Relevant academic research and scientific papers

P-Methoxybenzyl-N-phenyl-2,2,2-trifluoroacetimidate: A versatile reagent for mild acid catalyzed etherification

PMB-NPTFA 1a is a new month bench stable and powerful reagent for the formation of PMB ethers. Several alcohols were protected in high yields and short reaction times, using low reagent loading and small catalytic amounts of Bi(OTf)3. The mild

Disaccharide-containing macrocycles by click chemistry and intramolecular glycosylation

In this study o- and m-xylylene moieties in combination with a triazolylmethyl moiety have been successfully employed as a relatively rigid spacer system in intramolecular glycosylation reactions. Phenyl 3,4,6-tri-O-benzyl-2-O-propargyl-1-thio-D-glucopyra

Regioselective deprotection of p-methoxybenzyl ethers of furanose derivatives

Reaction of per-p-methoxybenzylated hexofuranoses and pentofuranoses with either a catalytic amount of tin chloride dihydrate (SnCl2·2H2O) or 0.5-10% solution of trifluoroaoetic acid in dichloromethane afforded regioselectively the corresponding monosaccharide derivatives having a single free hydroxyl group at C(5) in good yields.

Lewis Acid-Catalyzed Deprotection of p-Methoxybenzyl Ether

The p-methoxybenzyl protecting group was readily removed from alcohols and phenols using catalytic amounts of AlCl3 or SnCl2 · 2H2O in the presence of EtSH at room temperature. Under these mild conditions other protecting groups such as methyl and benzyl ethers, p-nitrobenzoyl esters, TBDPS ethers and isopropylidene acetal were unchanged.