2231-94-9Relevant academic research and scientific papers
Restudy of the Old Poly-2,5-di(benzoyloxy)styrene as a New Liquid Crystal Polymer
Zhou, Qi-Feng,Wan, Xinhua,Zhu, Xin-Long,Zhang, Fei,Feng, Xinde
, p. 107 - 118 (2007/10/02)
The 40 year old polymer, poly-2,5-di(benzoyloxy)styrene, has been restudied from the view point of the "mesogen-jacketed liquid crystal polymer".This old polymer was synthesized in 1952 as a precursor of an electron exchange polymer and is now found to be thermotropically liquid crystalline, from which the characteristic banded texture of rigid and semi-rigid liquid crystal polymers may be obtained.The monomer of this polymer, 2,5-di(benzoyloxy)styrene, was then also not realized as liquid crystalline, is now found to be liquid crystalline forming too.This finding offers probably the first example of liquid crystal rigid rod-like molecules with lateral but without terminal substitutions.The synthesis and primary characterization of a series of the closely related polymers poly-2,5-bisstyrenes are also reported. - Keywords: mesogen jacketed liquid crystal polymers, rigid side chain liquid crystal polymers, liquid crystal monomers, liquid crystal polymers, 2,5-bisstyrene, 2,5-bisstyrene, 2,5-bisstyrene, 2,5-di(benzoyloxy)styrene, poly-2,5-di(benzoyloxy)styrene
