223130-58-3Relevant academic research and scientific papers
Convenient one-pot synthesis of N,N′-bis(2-mercaptophenyl)pyridine-2,6-dicarboxamide and N-2-mercaptophenyl-2′-pyridinecarboxamide without protection of the thiol group(s)
Harrop, Todd C.,Rodriguez, Karina,Mascharak, Pradip K.
, p. 1943 - 1949 (2007/10/03)
A rapid and convenient procedure for the synthesis of N,N′-bis(2-mercaptophenyl)pyridine-2,6-dicarboxamide and N-2-mercaptophenyl-2′-pyridinecarboxamide from 2-aminothiophenol and the appropriate acid chloride is reported. The method is compatible only with aromatic acid chlorides containing a heteroatom. Aromatic acid chlorides with no heteroatom yield the corresponding 2-substituted benzothiazoles.
A synthetic analogue of the active site of Fe-containing nitrile hydratase with carboxamido N and thiolato S as donors: Synthesis, structure, and reactivities
Noveron,Olmstead,Mascharak
, p. 3247 - 3259 (2007/10/03)
As part of our work on models of the iron(III) site of Fe-containing nitrile hydratase, a designed ligand PyPSH4 with two carboxamide and two thiolate donor groups has been synthesized. Reaction of (Et4N)[FeCl4] with the d
