223130-75-4Relevant academic research and scientific papers
Studies in Lewis acid and LiClO4 (or Nafion-H) catalysed ionic Diels- Alder reactions of chiral and achiral olefinic acetals respectively
Kumareswaran,Vankar, Padmar S.,Reddy, M. Venkat Ram,Pitre, Sangeeta V.,Raja, Roy,Vankar, Yashwant D.
, p. 1099 - 1110 (1999)
Chiral olefinic acetals derived from crotonaldehyde undergo ionic Diels- Alder reaction giving the corresponding cycloadducts in moderate to good diastereoselectivities. A variety of achiral olefinic acetals react with isoprene and cyclopentadiene to form the cycloadducts in good to excellent yields when catalysed by 4M LiClO4 in nitromethane or by Nafion-H in dichloromethane.
