Tetrahedron p. 1099 - 1110 (1999)
Update date:2022-08-04
Topics:
Kumareswaran
Vankar, Padmar S.
Reddy, M. Venkat Ram
Pitre, Sangeeta V.
Raja, Roy
Vankar, Yashwant D.
Chiral olefinic acetals derived from crotonaldehyde undergo ionic Diels- Alder reaction giving the corresponding cycloadducts in moderate to good diastereoselectivities. A variety of achiral olefinic acetals react with isoprene and cyclopentadiene to form the cycloadducts in good to excellent yields when catalysed by 4M LiClO4 in nitromethane or by Nafion-H in dichloromethane.
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Doi:10.1016/S0960-894X(98)00181-4
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(1999)