223463-18-1

Basic information

• Product Name: 5,5''-bis<5-iodo-3-hexoxymethylphenyl>-2,2':6',2''-terpyridine
• Synonyms: 5,5''-bis<5-iodo-3-hexoxymethylphenyl>-2,2':6',2''-terpyridine
• CAS NO: 223463-18-1
• Molecular Weight: 865.636
• Mol File: 223463-18-1.mol

Chemical Properties

• CAS DataBase Reference: 5,5''-bis<5-iodo-3-hexoxymethylphenyl>-2,2':6',2''-terpyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5''-bis<5-iodo-3-hexoxymethylphenyl>-2,2':6',2''-terpyridine(223463-18-1)
• EPA Substance Registry System: 5,5''-bis<5-iodo-3-hexoxymethylphenyl>-2,2':6',2''-terpyridine(223463-18-1)

Safety Data

• Hazardous Substances Data: 223463-18-1(Hazardous Substances Data)

Upstream product

• 624-28-2 2,5-dibromopyridine 
• 223463-19-2 1-Bromo-3-hexyloxymethyl-5-iodobenzene 
• 223463-10-3 5,5''-dibromo-2,2',6',2''-terpyridine 

Relevant articles and documents

5,5″-disubstituted 2,2′:6′,2″-terpyridines through and for metal-mediated cross-coupling chemistry

The 0.3-5 g scale syntheses of the 2,2′:6′,2″-terpyridines 3, 6, 9, and 10 are described. The pyridine units are connected to one another by Pd-catalyzed cross-coupling reactions. This method allows the easy introduction of halogen, stannyl, and boronic ester functionalities at positions C-5 and C-5″; this results in a novel functionality pattern for terpyridines that considerably widens the applicability of this class of tridentate ligands for supra- and macromolecular applications. The feasibility of growth reactions with these novel terpyridines was demonstrated by the synthesis of compounds 12a-c.