22350-41-0Relevant articles and documents
Berman et al.
, p. 3325,3327, 3328 (1977)
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Loibner,H.,Zbiral,E.
, p. 713 - 716 (1978)
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Continuous-flow synthesis of vitamin D3
Fuse, Shinichiro,Tanabe, Nobutake,Yoshida, Masahito,Yoshida, Hayato,Doi, Takayuki,Takahashi, Takashi
scheme or table, p. 8722 - 8724 (2011/02/24)
A highly efficient, two-stage, continuous-flow synthesis of vitamin D 3 from provitamin D3 was achieved. The developed method afforded the desired product in high yield (HPLC-UV: 60%, isolated: 32%) and required neither intermediate purification nor high-dilution conditions. The Royal Society of Chemistry 2010.
Biomimetic oxidation of vitamin D by iron-sulfur model cluster and dioxygen system
Yamamoto,Imae,Yamada
, p. 4903 - 4906 (2007/10/02)
Oxidation of vitamin D3 with a combination of iron-sulfur protein model cluster, (n-Bu4N)2[Fe4S4(SPh)4], and molecular oxygen produced (5E)-10-oxo-10-norvitamin D3 and 8α-hydroxy-9,10-seco-4,6,10(19)-cholestatrien-3-one, a new type of vitamin D metabolites, mimicking biological oxidation.