22359-97-3Relevant articles and documents
The formation of HAlX2 (X = Cl, Br) in the thermolysis of intramolecularly coordinated alanes Me2N(CH2)3AlX2: A matrix isolation study
Mueller, Jens,Wittig, Bob
, p. 1807 - 1810 (2008/10/08)
High-vacuum thermolyses of the intramolecularly coordinated alanes Me2N(CH2)3AlX2 with X = Cl, Br (1, 2) were investigated with matrix isolation techniques. Among the products, which were identified with IR spectroscopy, ab initio calculations, and known literature data, are monomeric HAlCl2 and HAlBr2. The experimental vibrational frequencies of these hydrides matches well the calculated harmonic frequencies at the MP2(fc)/6-311G+(2d, p) and B3LYP/6-311G+(2d, p) level of theory. Beside the monomeric HAlX2, the argon matrices of the thermolysis experiments contained CH4, HCN, H2C=CH2, H2C=NMe, [H2CCHCH2]?, H2C=CHCH3, and AlXn (n = 1-3; X = Cl or Br).
