22472-36-2

Usage

InChI:InChI=1/C10H22Si2/c1-9(11(3,4)5)10(2)12(6,7)8/h1-2H2,3-8H3

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 108965-15-7 C₁₄H₂₂N₂O₂SSi 
• 754-05-2 ethenyltrimethylsilane 
• 18922-04-8 6-iodohex-1-ene 
• 13683-41-5 1-bromo-1-(trimethylsilyl)ethene 
• 143-15-7 1-dodecylbromide 
• 43209-86-5 3-trimethylsilyl-3-buten-2-one 
• 66374-47-8 3-trimethylsilanyl-but-3-en-2-ol 
• 593-60-2 Vinyl bromide 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 91312-27-5 2,3-Bis(trimethylstannyl)-1,3-butadiene 
• 2441-29-4 (1-chloro-vinyl)-trimethyl-silane 

Downstream Products

• 69916-34-3 (5-methyl-2-phenylfuran-3-yl)(phenyl)methanone 
• 344320-91-8 (2-methyl-5-phenylfuran-3-yl)(phenyl)methanone 
• 34721-89-6 2-methyl-5-phenyl-furan 
• 108965-18-0 4,5-Bis-trimethylsilanyl-cyclohexa-1,4-diene-1,2-dicarboxylic acid dimethyl ester 
• 108965-17-9 2-Phenyl-5,6-bis-trimethylsilanyl-3a,4,7,7a-tetrahydro-isoindole-1,3-dione 

Relevant academic research and scientific papers

Iron-catalyzed cross-coupling of alkyl halides with alkenyl Grignard reagents

(Chemical Equation Presented) Cheap and safe: An iron-catalyzed cross-coupling reaction between alkyl halides and alkenyl Grignard reagents is described. This C-C bond coupling reaction is promoted by the cheap and nontoxic FeCl3 and displays good tolerance against various functional groups.

Synthesis of 2,3-disubstituted 1,3-butadienes from organotin precursors and butadienyllithium reagents. Diels-alder reactivity

1,4-Bis(trimethylstannyl)-2-butyne (1) and 2,3-bis(trimethylstannyl)-1,3-butadiene (2), versatile synthons for the 2,3-dianion of 1,3-butadiene, have been prepared from either 1,4-dichloro-2-butyne or 2,3-dichloro-1,3-butadiene by reaction with 2 equiv of

Stereospecific 1,4-polymerization of 2,3-bis(trimethylsilyl)-1,3-butadiene

Polymerization of 2,3-bis(trimethylsilyl)-1,3-butadiene in hexane/HMPA catalyzed by n-butyllithium yields trans-1,4-poly.This polymer has been characterized by 1H, 13C and 29Si NMR as well as IR spectroscopy and elemental analysis.The stereochemistry of the carbon-carbon double bonds has been established by protodesilation of the polymer with HI.The molecular weight distribution of the polymer has been determined by gel permeation chromatography and its thermal stability by thermogravimetric analysis.

ALTERNATIVE SYNTHESES AND DIELS-ALDER REACTIONS OF 2,3-Bis(TRIMETHYLSILYL)BUTA-1,3-DIENE

The title compound has been prepared by two routes and some Diels-Alder reactions of it investigated.

Organotin Chemistry. Preparation of 2,3-Disubstituted 1,3-Butadienes Using 2,3-Bis(trimethylstannyl)-1,3-butadiene and 1,4-Bis(trimethylstannyl)-2-butyne

2,3-Bis(trimethylstannyl)-1,3-butadiene is a versatile synthon for the 2,3-dianion of 1,3-butadiene; mono and bis derivatizations with electrophiles such as halosilanes, disulfides, selenium, alkyl halides, aldehydes, and ketones have been carried out.