69916-34-3

Basic information

• Product Name: Methanone, (5-methyl-2-phenyl-3-furanyl)phenyl-
• CAS NO: 69916-34-3
• Molecular Formula: C18H14O2
• Molecular Weight: 262.308
• Mol File: 69916-34-3.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Methanone, (5-methyl-2-phenyl-3-furanyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (5-methyl-2-phenyl-3-furanyl)phenyl-(69916-34-3)
• EPA Substance Registry System: Methanone, (5-methyl-2-phenyl-3-furanyl)phenyl-(69916-34-3)

Safety Data

• Hazardous Substances Data: 69916-34-3(Hazardous Substances Data)

Upstream product

• 120-46-7 1,3-diphenylpropanedione 
• 106-96-7 propargyl bromide 
• 98-83-9 isopropenylbenzene 
• 81396-47-6 2-benzoyl-1-phenylpentane-1,4-dione 
• 19823-69-9 1,3-diphenyl-2-(prop-2-yn-1-yl)propane-1,3-dione 
• 1469-70-1 allyl ethyl carbonate 
• 7338-94-5 1,3-diphenyl-2-propynone 
• 65007-60-5 C₁₈H₁₄O₂ 
• 123883-74-9 phenyl(2-phenyl-5-((phenylselanyl)methyl)-4,5-dihydrofuran-3-yl)methanone 
• 22472-36-2 2,3-bis(trimethylsilyl)-buta-1,3-diene 
• 98-88-4 benzoyl chloride 
• 59875-97-7 2-allyl-1,3-diphenyl-1,3-propanedione 
• 122132-54-1 (5-(iodomethyl)-2-phenyl-4,5-dihydrofuran-3-yl)(phenyl)methanone 

Relevant articles and documents

Synthesis of 3-Carbonyl Trisubstituted Furans via Pd-Catalyzed Aerobic Cycloisomerization Reaction: Development and Mechanistic Studies

Herein, we report the synthesis of 3-carbonyl-trisubstituted furans via Pd-catalyzed oxidative cycloisomerization reactions of 2-alkenyl-1,3-dicarbonyl scaffolds, using molecular oxygen as the sole oxidant to regenerate active palladium catalytic species, featuring good functional tolerance and mild reaction conditions. Deep investigation of intermediates and transition states of the reaction mechanism were conducted via experimental and DFT studies, providing a detailed mechanistical profile. The new developed methodology presents a greener alternative to Wacker-type cycloisomerizations and avoids the use of stoichiometric amounts of oxidants and strong acid additives.

nBu4NI-catalyzed C–C bond formation to construct 2-carbonyl-1,4-diketones under mild conditions

An nBu4NI-catalyzed oxidative cross-dehydrogenative-coupling of β-dicarbonyl compounds with acetone under mild reaction conditions is described. This methodology provides a straightforward pathway to synthesize 2-carbonyl-1,4-diketones and feat

Thulium Triflate Catalyzed Hydration of 2-Substituted 4-Alkynones

We report on a facile synthetic route for the preparation of substituted 1,4-diketones by thulium triflate mediated hydration of substituted 4-alkynones in MeNO2 at 25 °C for five hours. The products were obtained in moderate to high yields.