22472-78-2

Upstream product

• 1753-40-8 (R)-4-menthen-3-one 
• 29685-68-5 (1R,4R,6R)-1-isopropyl-4-methyl-7-oxa-bicyclo[4.1.0]heptan-2-one 
• 619-52-3 (1R)-menth-3-ene 
• 555-31-7 aluminum isopropoxide 

Downstream Products

• 1678-82-6 trans-1,4-menthane 
• 2216-51-5 (-)-menthol 
• 10458-14-7 (2R,5S)-menthone 
• 215032-10-3 (1R,3S)-5-methyl-2-(1-methylethyl)cyclohexane-1,3-diol 
• 215032-10-3 (1R,3R)-5-methyl-2-(1-methylethyl)cyclohexane-1,3-diol 
• 1610361-68-6 N-[(1R,5R)-2-(1-methylethyl)-5-methyl-2-cyclohexenyl]acetamide 
• 1610361-69-7 N-[(1S,5R)-2-(1-methylethyl)-5-methyl-2-cyclohexenyl]acetamide 
• 1496556-91-2 C₁₄H₂₄O₂ 

Relevant academic research and scientific papers

Reactions of (R)-4-Menthen-3-one with Aluminum and Boron-Containing Hydrides

It was shown that the most effective and stereospecific hydride reductant for (R)-4-menthen-3-one to (1R,3R)-menthen-3-ol was i-Bu2AlH whereas the complex BH3·THF, which exhibited the same properties relative to the substrate carbony

Thiylation of (R)-4-menthen-3-one and its derivatives

Thiylation of (R)-4-menthen-3-one and its derivatives was studied. New sulfides and sulfoxides of the menthane series were synthesized.

Convergent synthesis of the spiroketal core of the HIV-1 protease inhibitors the didemnaketals

A stereocontrolled and efficient synthetic approach to the spiroketal compound 4a and its C1″-epimer 4b, the core of the HIV-protease inhibitor didemnaketals isolated from the ascidian Didemnum sp., is developed through a multistep approach from natural L