22541-63-5Relevant articles and documents
Recovery of radioactive cobalt from aqueous EDTA solutions using concentrated ozone
Seliverstov,Lagunova,Ershov,Gelis,Basiev
, p. 326 - 328 (2009)
Oxidative decomposition of EDTA in aqueous solution under the action of ozone was studied. Conditions providing complete decomposition of EDTA and precipitation of radioactive cobalt in the form of hydroxide were found.
Jonassen, H. B.,Frey, F. W.
, p. 2454 - 2455 (1957)
Field, F. H.,Vosburgh, W. C.
, p. 2398 - 2401 (1949)
Kinetics of Silver(II) Oxidation of Metal Cations
Arselli, Patrizia,Baiocchi, Claudio,Mentasti, Edoardo,Coe, John S.
, p. 475 - 478 (2007/10/02)
The oxidation of Fe2+, Mn2+, Co2+, Ce3+, and VO2+ by silver(II) has been investigated with a stopped-flow technique.The reactions of Mn2+ and Ce3+ occur through two competitive paths involving Ag2+ and AgOH+.For the other cations a single pathway with Ag2+ as oxidant has been observed.An inner-sphere interaction mechanism is proposed and discussed with reference to the electron configuration of the reductant and to the behaviour predicted by the Marcus cross relation.
Kinetics of Oxidation of Cobalt(II) by Iron(III) in Presence of 2,2'-Bipyridyl
Subbaiah, K. V.,Srinivas, K.,Subba Rao, P. V.
, p. 399 - 401 (2007/10/02)
The reaction between iron(III) and cobalt(II) in the presence of 2,2'-bipyridyl has been investigated spectrophotometrically.The rate-law has been found to be: .The added anions accelerate the reaction in the order: Cl(-) > Br(-) > ClO4(-).The activation energy and entropy of activation have been found to be 8.0 +/- 0.5 kcal mol-1 and -13 +/- 1.0 cal deg-1 mol-1, respectively.An outer-sphere electron-transfer mechanism has been proposed.