225779-49-7Relevant academic research and scientific papers
Diversity-oriented synthesis of bicyclic and tricyclic alkaloids
Diaz-Gavilan, Monica,Galloway, Warren R. J. D.,O'Connell, Kieron M. G.,Hodkingson, James T.,Spring, David R.
, p. 776 - 778 (2010)
A diversity-oriented synthesis involving a cascade sequence, taking linear aminoalkenes to polycyclic scaffolds reminiscent of natural alkaloids, is presented.
Enantioselective Synthesis of Tropanes: Br?nsted Acid Catalyzed Pseudotransannular Desymmetrization
Carrillo, Luisa,Merino, Pedro,Reyes, Efraim,Rodriguez, Sandra,Tejero, Tomás,Uria, Uxue,Vicario, Jose L.
supporting information, p. 6780 - 6784 (2020/03/19)
The enantioselective synthesis of tropanols has been accomplished through chiral phosphoric acid catalyzed pseudotransannular ring opening of 1-aminocyclohept-4-ene-derived epoxides. The reaction proceeds together with the desymmetrization of the starting
Two-directional synthesis as a tool for diversityoriented synthesis: Synthesis of alkaloid scaffolds
O'Connell, Kieron M. G.,Diaz-Gavilan, Monica,Galloway, Warren R. J. D.,Spring, David R.
supporting information; scheme or table, p. 850 - 860 (2012/07/16)
Two-directional synthesis represents an ideal strategy for the rapid elaboration of simple starting materials and their subsequent transformation into complex molecular architectures. As such, it is becoming recognised as an enabling technology for divers
A two-directional approach to the anatoxin alkaloids: Second synthesis of homoanatoxin and efficient synthesis of anatoxin-a
Roe, Stephen J.,Stockman, Robert A.
supporting information; experimental part, p. 3432 - 3434 (2009/02/05)
Total syntheses of the potent neurotoxins, environmental hazards, and biochemical probes anatoxin-a and homoanatoxin have been achieved from a common intermediate using a combined two-directional synthesis-tandem reaction strategy which includes key advan
Asymmetric synthesis of (-)-anatoxin-a via an asymmetric cyclization using a new ligand for Pd-catalyzed alkylations
Trost, Barry M.,Oslob, Johan D.
, p. 3057 - 3064 (2007/10/03)
Palladium-catalyzed asymmetric allylic alkylations have been explored in the context of medium-sized ring substrates, intramolecular vs intermolecular processes involving attack on a formally meso π-allyl intermediate in the desymmetrization, and the pres
