22661-28-5Relevant academic research and scientific papers
S -Tetrazine: Robust and Green Photoorganocatalyst for Aerobic Oxidation of N,N-Disubstituted Hydroxylamines to Nitrones
Lyu, Jiyuan,Le, Tuan,Claraz, Aurélie,Allain, Clémence,Audebert, Pierre,Masson, Géraldine
supporting information, p. 177 - 181 (2021/12/06)
Efficient photocatalytic aerobic oxidative dehydrogenation reactions of N,N-disubstituted hydroxylamines to nitrones were developed with an in situ generated photocatalyst based on commercially available 3,6-dichlorotetrazine. This process affords a wide range of nitrones in high yields under mild conditions. In addition, an oxidative (3+3) cycloaddition between an oxyallyl cation precursor and a hydroxylamine was also developed.
Cycloaddition of nitrones with arynes generated from benzobisoxadisilole or 2,3-naphthoxadisilole
Wu, Kaicheng,Chen, Yali,Lin, Yibei,Cao, Weiguo,Zhang, Min,Chen, Jie,Lee, Albert W.M.
experimental part, p. 578 - 582 (2010/09/05)
1,3-Dipolar cycloaddition of nitrones with arynes generated in situ from benzobisoxadisilole or 2,3-naphthoxadisilole afforded the oxadisilole fused benzo[d]isoxazoline or the naphtho[2,3-d]isoxazoline derivatives at room temperature in good yields.
