22663-61-2Relevant articles and documents
From alkenes to alcohols by cobalt-catalyzed hydroformylation-reduction
Achonduh, George,Yang, Qian,Alper, Howard
supporting information, p. 1241 - 1246 (2015/03/05)
The cobalt-catalyzed hydroformylation of alkenes in the presence of a range of novel cyclic phosphine ligands was investigated. The effect of various parameters such as solvents, additives, cobalt/phosphine ratio, CO/H2 (1:2), and nature of the alkenes was examined. The results revealed that both terminal and internal alkenes are hydroformylated in high yields to give mainly linear products at moderate temperature and syn gas pressure. The linearity ranges from 43 to 85%, with Lim-10 giving the highest proportion of linear product.
Formic acid: A promising bio-renewable feedstock for fine chemicals
Mura, Manuel G.,Luca, Lidia De,Giacomelli, Giampaolo,Porcheddu, Andrea
supporting information, p. 3180 - 3186 (2013/01/15)
In light of the growing scarcity of petroleum-based raw materials, carbon dioxide (CO2) is becoming increasing attractive as organic carbon source. In this perspective, formic acid (HCOOH) might be an interesting bio-renewable solution to store, transport, and activate carbon dioxide for the synthesis of value-added chemicals. Herein, HCOOH has been successfully used as C1 building block for the synthesis of a library of alcohols via a catalysed oxo-synthesis, under green experimental conditions. Copyright
