22688-04-6

Basic information

• Product Name: (E)-1-(3-methoxyprop-1-en-1-yl)-4-methylbenzene
• Synonyms: (E)-1-(3-methoxyprop-1-en-1-yl)-4-methylbenzene
• CAS NO: 22688-04-6
• Molecular Weight: 162.232
• Mol File: 22688-04-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-1-(3-methoxyprop-1-en-1-yl)-4-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(3-methoxyprop-1-en-1-yl)-4-methylbenzene(22688-04-6)
• EPA Substance Registry System: (E)-1-(3-methoxyprop-1-en-1-yl)-4-methylbenzene(22688-04-6)

Safety Data

• Hazardous Substances Data: 22688-04-6(Hazardous Substances Data)

Upstream product

• 20754-20-5 3-p-tolyl-acrylic acid methyl ester 
• 104-87-0 4-methyl-benzaldehyde 
• 1866-39-3 trans-p-methylcinnamic acid 
• 97585-04-1 ethyl (E)-3-(4-methylphenyl)acrylate 
• 122058-30-4 p-methylcinnamyl alcohol 
• 74-88-4 methyl iodide 
• 67-56-1 methanol 
• 77134-00-0 (E)-4-methylcinnamyl acetate 
• 2749-96-4 4-methylphenylallene 
• 22554-03-6 trans-3-Ethoxycarbonylamino-1-(p-tolyl)-propen 
• 124-41-4 sodium methylate 

Downstream Products

• 1291104-89-6 acetic acid (1S,2S)-2-acetoxy-3-methoxy-1-(4-methylphenyl)propyl ester 
• 1291104-94-3 acetic acid (1R,2S)-2-acetoxy-3-methoxy-1-(4-methylphenyl)propyl ester 
• 56578-35-9 4-methyl-cinnamaldehyde 

Relevant articles and documents

Oxoammonium-Mediated Allylsilane–Ether Coupling Reaction

A new C(sp3)?H functionalization reaction consisting of the oxidative α-allylation of allyl- and benzyl- methyl ethers has been developed. The C?C coupling could be carried out under mild conditions thanks to the use of cheap and green oxoammonium salts. The scope of the reaction was studied over 27 examples, considering the nature of the substituents on the two coupling partners.

Enantioselective Prevost and Woodward reactions using chiral hypervalent iodine(iii): Switchover of stereochemical course of an optically active 1,3-dioxolan-2-yl cation

Optically active 1,3-dioxolan-2-yl cation intermediates were generated during enantioselective dioxyacetylation of alkene with chiral hypervalent iodine(III). Regioselective attack of a nucleophile toward the intermediate resulted in reversal of enantioselectivity of the dioxyacetylation. The Royal Society of Chemistry.

Gold-catalyzed intermolecular hydroalkoxylation of allenes; difference in mechanism between hydroalkoxylation and hydroamination

A wide range of alcohols 2 react with various allenes 1 in the presence of ClAuPPh3/AgOTf catalyst at ambient temperature without solvent to produce allylic ethers 3. Contrary to the hydroamination, which proceeds through high chiral-face selec