226909-63-3

Upstream product

• 941-55-9 4-toluenesulfonyl azide 
• 99685-96-8 fullerene-C₆₀ 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 70-55-3 toluene-4-sulfonamide 
• 175970-03-3 N-(4'-methylphenylsulfonyl)aziridino[2'3':1,2][60]fullerene 
• 127-65-1 chloroamine-T 
• 127-52-6 chloramine-B 

Downstream Products

• 99685-96-8 fullerene-C₆₀ 
• 175970-03-3 N-(4'-methylphenylsulfonyl)aziridino[2'3':1,2][60]fullerene 

Relevant academic research and scientific papers

Metal-free aziridination of styrene derivatives with iminoiodinane catalyzed by a combination of iodine and ammonium iodide

The metal-free catalytic aziridination of styrene derivatives with N-tosyliminophenyliodinane (PhI=NTs) in the presence of a combination of I 2 and tetrabutylammonium iodide (TBAI) is reported. In situ generated TBAI3 from I2/s

Regioselective Diels-Alder reaction to open-cage ketolactam derivatives of C60

Open-cage ketolactam fullerenes reacted with dienes on the rim of the orifice both regio- and stereoselectively. Unequivocal evidence for the structure of the Diels-Alder adduct was provided by 2D INADEQUATE 13C NMR studies on 13C enriched material, as well as via DFT-GIAO calculations. The theoretical calculations successfully model the regioselective and the endo stereoselective reaction, predicting molecular orbital control along with a repulsive steric interaction between the substituents on the nitrogen atom and those on the diene.

Hypervalent iodine reagent mediated reaction of [60]fullerene with amines

The hypervalent iodine reagent mediated reaction of C60 with various readily available amines for the easy preparation of iminofullerenes has been developed. The reaction between C60 and sulfonamides can be effectively controlled to

Selective functionalization of fullerenes with N,N-dihalosulfonamides as an N1 unit: Versatile syntheses of aza[60]fulleroids and aziridino[60]fullerenes and their application to photovoltaic cells

Highly selective and versatile methods for the synthesis of aza[60]fulleroids and aziridino[60]fullerenes from C60 have been developed. The reactions utilized N,N-dihalosulfonamides as an N1 source. The photophysical, electrochemical

Organosulfur-based fullerene materials

Chemical functionalizations of an endohedral metallofullerene, La 2@Ih-C80, and an empty fullerene, C 60, are demonstrated using organosulfur compounds. A novel donor-acceptor system of La2@Ih/s

The ionic introduction of an N1 unit to C60 and a unique rearrangement of aziridinofullerene

A new chloramine-based aziridination of C60 and unique rearrangement of aziridinofullerene to azafulleroid is described. The ionic introduction of an N1 unit to C60via an addition-cyclization mechanism was first achieved under mild conditions; the combination of chloramine and MS4A resulted in the promising rearrangement of aziridinofullerene to azafulleroid, and the isomerization could be performed catalytically. The Royal Society of Chemistry.

[2+1] Cycloaddition of nitrene onto C60 revisited: Interconversion between an aziridinofullerene and an azafulleroid

(Figure Presented) An open and closed case: The reversible interconversion of a [1,2]aziridinofullerene and a [1,6]azafulleroid represents the first such example for a monosubstituted fullerene. While the [1,2]aziridinofullerene rearranges thermally to th

Preparation and characterization of sulfonyl-azafulleroid and sulfonylaziridino-fullerene derivatives

Thermolysis of several sulfonyl azides in the presence of C60 leads either to aza[60]fulleroids or to mixtures of aza[60]-fulleroids and corresponding aziridino-fullerenes, depending on the substituent at the sulfonyl group. In all cases, 1,2-c