22774-95-4

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 134-32-7 1-amino-naphthalene 
• 103-54-8 cinnamyl acetate 
• 104-54-1 3-Phenylpropenol 
• 4392-24-9 Cinnamyl bromide 
• 837-78-5 N-trifluoroacetyl-α-naphthylamine 
• 78977-68-1 N-(γ-phenylallyl)-N-trifluoroacetyl-1-naphthylamine 

Downstream Products

• 5278-58-0 2-phenyl-benzo[H]quinoline 
• 134-32-7 1-amino-naphthalene 
• 78977-74-9 2-(1-Phenyl-allyl)-naphthalen-1-ylamine 
• 78977-75-0 2-((E)-3-Phenyl-allyl)-naphthalen-1-ylamine 
• 78977-76-1 4-((E)-3-Phenyl-allyl)-naphthalen-1-ylamine 

Relevant academic research and scientific papers

PH-Mediated Selective Synthesis of N-Allylic Alkylation or N-Alkylation Amines with Allylic Alcohols via an Iridium Catalyst in Water

Amination of allylic alcohols is an effective approach in the facile synthesis of N-allylic alkylation or N-alkylation amines. Recently, a series of catalysts were devised to push forward this transformation. However, current synthetic methods are typical

Exclusive chemoselective reduction of imines in the coexistence of aldehydes using AuNPore catalyst

Aldimines (R1HC=NR2) were reduced in the coexistence of aldehydes (R1CHO) with 100% chemoselectivity by the use of AuNPore giving corresponding amines (R1H2C-NHR2) in high chemical yields.

PEG-4000-promoted palladium-catalyzed N-allylation in water: Aminonaphthalene as an example

An environmentally friendly, efficient catalytic process using palladium associated with ligands in a PEG4000-water system leading to N-allylation was described in this study. PEG-4000 was found to improve the palladium-catalyzed allylic amination of allylic acetates with aminonaphthalenes and gave overall good to high yields of the corresponding N-allylic aminonaphthalenes. Copyright

Pd(OAc)2/dppf as an efficient and highly active catalyst for the allylation of amines, alcohols and carboxylic acids with 1-phenyl-1-propyne

Pd(OAc)2/1,1′-bis(diphenylphosphino)ferrocene as an efficient, highly active catalyst for the allylation of amines, alcohols and carboxylic acids with 1-phenyl-1-propyne has been developed. The effect of various reaction parameters, such as ligand, time, solvent, temperature, metal: ligand ratio and catalyst concentration on yields of the product were investigated. The optimized procedure works well under mild operating conditions and permits rapid generation of a library for various allylated products.

Thermal Rearrangement of N-(Substituted allyl)-1-naphthylamines

The title reaction was examined and the results were compared with those of the thermal reaction of the corresponding N-tosyl derivatives.