228404-68-0Relevant academic research and scientific papers
A diastereoselective palladium-catalyzed acetoxylation of racemic allyl phosphorus compounds
Principato, Bruno,Attolini, Mireille,Peiffer, Gilbert,Maffei, Michel
, p. 229 - 238 (1998)
The palladium-catalyzed acetoxylation of chiral racemic allyl phosphorus compounds 1 and 2 occurs diastereoselectively, showing that the presence of a chiral moiety on phosphorus can influence the stereochemical course of the reaction. Although the yield obtained from 1 is very low, the use of 2 leads to a 50% diastereomeric excess and 86% yield.
