Phosphorus, Sulfur and Silicon and the Related Elements p. 229 - 238 (1998)
Update date:2022-08-03
Topics:
Principato, Bruno
Attolini, Mireille
Peiffer, Gilbert
Maffei, Michel
The palladium-catalyzed acetoxylation of chiral racemic allyl phosphorus compounds 1 and 2 occurs diastereoselectively, showing that the presence of a chiral moiety on phosphorus can influence the stereochemical course of the reaction. Although the yield obtained from 1 is very low, the use of 2 leads to a 50% diastereomeric excess and 86% yield.
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