22865-51-6

Basic information

• Product Name: N,N-dimethyl-4-[(4-nitrophenyl)sulfanyl]aniline
• CAS NO: 22865-51-6
• Molecular Formula: C₁₄H₁₄N₂O₂S
• Molecular Weight: 274.3382
• Mol File: 22865-51-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 452.2°C at 760 mmHg
• Flash Point: 227.3°C
• Density: 1.27g/cm³
• Vapor Pressure: 2.29E-08mmHg at 25°C
• Refractive Index: 1.652
• CAS DataBase Reference: N,N-dimethyl-4-[(4-nitrophenyl)sulfanyl]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-4-[(4-nitrophenyl)sulfanyl]aniline(22865-51-6)
• EPA Substance Registry System: N,N-dimethyl-4-[(4-nitrophenyl)sulfanyl]aniline(22865-51-6)

Safety Data

• Hazardous Substances Data: 22865-51-6(Hazardous Substances Data)

Upstream product

• 937-32-6 4-nitrobenzenesulfenyl chloride 
• 121-69-7 N,N-dimethyl-aniline 
• 101-59-7 4-amino-4'-nitrodiphenyl sulfide 
• 74-88-4 methyl iodide 
• 40208-36-4 N-(p-nitrophenylthio)morpholine 
• 5397-29-5 4-(N,N-dimethylamino)phenyl disulfide 
• 586-78-7 para-nitrophenyl bromide 

Downstream Products

• 68253-28-1 4-Dimethylamino-4'-iod-diphenylsulfid 
• 68253-27-0 4-[(4-bromophenyl)sulfanyl]-N,N-dimethylaniline 
• 68253-26-9 4-(4-chlorophenylthio)-N,N-dimethylbenzenamine 
• 63029-16-3 (4-amino-phenyl)-(4-dimethylamino-phenyl)-sulfide 

Relevant articles and documents

Reaction of sulfenamides with N,N-dimethylaniline in the presence of phosphorus(v) oxochloride

Reaction of arylsulfenamides with N, N-dimethylaniline in the presence of POCl3 at room temperature affords unsymmetrical diaryl sulfide, only para-substituted N, N-dimethylanilines being formed.

SYNTHESIS OF DIARYLSELENIDES AND DIARYLSULFIDES UNDER PHASE TRANSFER CONDITIONS

Diarylselenides and diarylsulfides are synthesized from the corresponding diaryldiselenide and diaryldisulfide by reduction with aminoiminomehanesulfinic acid, and reaction with activated aryl halides under phase transfer conditions.The reactions yields vary from good to excellent.