68253-26-9

Basic information

• Product Name: Benzenamine, 4-[(4-chlorophenyl)thio]-N,N-dimethyl-
• CAS NO: 68253-26-9
• Molecular Formula: C14H14ClNS
• Molecular Weight: 263.791
• Mol File: 68253-26-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-[(4-chlorophenyl)thio]-N,N-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-[(4-chlorophenyl)thio]-N,N-dimethyl-(68253-26-9)
• EPA Substance Registry System: Benzenamine, 4-[(4-chlorophenyl)thio]-N,N-dimethyl-(68253-26-9)

Safety Data

• Hazardous Substances Data: 68253-26-9(Hazardous Substances Data)

Upstream product

• 7152-80-9 4-(dimethylamino)benzenethiocyanate 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 2751-25-9 p-chlorophenylsulfonyl hydrazide 
• 121-69-7 N,N-dimethyl-aniline 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 106-54-7 p-Chlorothiophenol 
• 63029-16-3 (4-amino-phenyl)-(4-dimethylamino-phenyl)-sulfide 
• 22865-51-6 4-dimethylamino-4'-nitrodiphenyl sulfide 

Downstream Products

• 1044572-72-6 [4-(4-chloro-benzenesulfinyl)phenyl]dimethylamine 
• 1044572-81-7 5'-chloro-2'-((4-(dimethylamino)phenyl)sulfinyl)-[1,1'-biphenyl]-4-carbonitrile 
• 1309446-19-2 4-((4-chloro-2-(phenylethynyl)phenyl)sulfinyl)-N,N-dimethylaniline 
• 1309446-20-5 4-((4-chloro-2-((trimethylsilyl)ethynyl)phenyl)sulfinyl)-N,N-dimethylaniline 
• 1309446-37-4 ethyl 2-(4-chloro-2-((trimethylsilyl)ethynyl)benzyl)acrylate 

Relevant articles and documents

Electrochemical access to aryl sulfides from aryl thiols and electron-rich arenes with the potassium iodide as a mediator

An indirect electrooxidation method catalyzed by potassium iodide at a low potential for the synthesis of aryl sulfides from aryl thiols and electron-rich arenes has been developed. Cyclic voltammetry was carried out to investigate the electrocatalytic ac

Electrocatalytic Oxidant-Free Dehydrogenative C?H/S?H Cross-Coupling

An environmentally friendly electrocatalytic protocol has been developed for dehydrogenative C?H/S?H cross-coupling. This method enabled C?S bond formation under catalyst- and oxidant-free conditions. Under undivided electrolysis conditions, various aryl/heteroaryl thiols and electron-rich arenes afforded the C?S bond-formation products in 24–99 % yield. A preliminary mechanistic study indicated that the generation of aryl radical cation intermediates is key to the success of this transformation.

Iodine-Mediated Synthesis of Aromatic Thioethers with Aromatic Amines and Sulfonyl Hydrazides in High Regioselectivity via C(sp2)-H Bond Functionalization

An iodine-mediated synthesis of aromatic thioethers from aromatic amines and sulfonyl hydrazides via C(sp2)-H bond functionalization and C-S bond formation has been developed. In this procedure, various substituents on the sulfonyl hydrazides, such as alkyl, methoxyl, chloro, bromo and fluoro groups, and aromatic amines are tolerated in the thiolation which generates the desired products in moderate to good yields.