22882-57-1Relevant academic research and scientific papers
Studies directed towards the preparation of probes for the photoaffinity labelling of gibberellin receptors
Crow, James R.,Chandler, Peter M.,Mander, Lewis N.
experimental part, p. 471 - 488 (2011/10/31)
Model studies for the preparation of photoaffinity probes designed to explore the nature of gibberellin receptor sites have provided a wide range of gibberellin derivatives that should afford useful scaffolds incorporating auxiliary groups attached to C-2
CHLOROETHOXY(TRIMETHYL)SILANE : A HARD-BASE TRAP WHICH PRESERVES TMS ETHER GROUPS AND IMPROVES THE WITTIG METHYLENATION OF GIBBERELLINS
Mander, Lewis N.,Turner, John V.
, p. 4149 - 4152 (2007/10/02)
A reagent, 2-chloroethoxy(trimethyl)silane (CETS), has been devised which ensures the preservation of TMS ether groups during Wittig methylenation in protic media and which makes this formerly capricious reaction with 16-keto gibberellins a reliable and straightforward procedure.
