22882-91-3

Usage

Uses

Used in Perfumery and Flavoring Industry:
(E)-1-ethoxy-3,7-dimethylocta-2,6-diene is used as a fragrance ingredient for its floral, fruity scent, enhancing the aroma of perfumes and flavorings.
Used in Pesticide Industry:
(E)-1-ethoxy-3,7-dimethylocta-2,6-diene is used as an insecticide and antimicrobial agent in household and agricultural pesticides, providing effective pest control while being relatively safe for human and environmental health.
Used in Essential Oils:
(E)-1-ethoxy-3,7-dimethylocta-2,6-diene is used as a component in various essential oils, contributing to their unique scents and properties.

Upstream product

• 4490-10-2 geranyl chloride 
• 64-17-5 ethanol 
• 6138-90-5 geranyl bromide 
• 32659-10-2 (E)-1-bromo-4-ethoxy-2-methyl-but-2-ene 
• 870-63-3 prenyl bromide 
• 75-03-6 ethyl iodide 
• 78055-70-6 trimethyl[(E)-3,7-dimethylocta-2,6-dienyl]silane 
• 74589-92-7 linalyl carbonate 
• 4648-54-8 trimethylsilylazide 
• 74-96-4 ethyl bromide 
• 106-24-1 Geraniol 
• 78-39-7 Triethyl orthoacetate 
• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 126-91-0 linalool 

Downstream Products

• 141-27-5 3,7-dimethyl-2,6-octadienal 
• 106-24-1 Geraniol 

Relevant academic research and scientific papers

Asymmetric Traceless Petasis Borono-Mannich Reactions of Enals: Reductive Transposition of Allylic Diazenes

The traceless Petasis borono-Mannich reaction of enals, sulfonylhydrazines, and allylboronates, catalyzed by chiral biphenols, results in an asymmetric reductive transposition of the in situ generated allylic diazene. Acyclic 1,4-diene products bearing either alkyl- or aryl-substituted benzylic stereocenters are afforded in excellent yields and enantiomeric ratios of up to 99:1. The use of crotylboronates in the reaction results in concomitant formation of two stereocenters in either a 1,4-syn or anti relationship from the corresponding E- or Z-crotylboronate used in the reaction. The use of β-monosubstituted enals in the asymmetric traceless Petasis borono-Mannich reaction of crotylboronates installs tertiary methyl-bearing stereocenters in good yields and high enantioselectivities.

Iodine catalyzed selective O-alkylation of alcohols with orthoesters

In the present communication O-alkylation of a number of allylic and benzylic alcohols has been described.

PALLADIUM(0)-CATALYZED AZIDATION OF ALLYL ESTERS WITH TRIMETHYLSILYL AZIDE

Palladium(0)-catalyzed reaction of allyl esters with trimethylsilyl azide gives, under anhydrous conditions, the corresponding allyl azides.

ELECTROCHEMICAL OXIDATION OF ORGANOSILICON COMPOUNDS I. OXIDATIVE CLEAVAGE OF CARBON-SILICON BOND IN ALLYLSILANES AND BENZYLSILANES

Electrochemical oxidation of allylsilanes and benzylsilanes in the presence of alcohol, carboxylic acid, or water resulted in cleavage of the carbon-silicon bond and formation of the corresponding ether, ester, or alcohol, respectively.