22984-61-8

Upstream product

• 3709-20-4 dimethyl 2-phenyl-1,1-cyclopropanedicarboxylate 
• 75326-15-7 (2-bromo-1-phenylethyl)dimethylsulphonium bromide 
• 100-42-5 styrene 
• 104-88-1 4-chlorobenzaldehyde 
• 1073-67-2 4-vinylbenzyl chloride 
• 108-59-8 malonic acid dimethyl ester 
• 38330-80-2 monomethyl monopotassium malonate 
• 145838-86-4 bis(methoxycarbonyl)(phenyliodinio)methanide 

Relevant academic research and scientific papers

Sonochemical Lactonization of Olefins with Ceric Ammonium Nitrate and Monomethyl Ester of Malonic Acid

Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation.Comparative results are reported, for activated olefins

Lactonization of olefins mediated by Mn(OAc)3: A sonochemical approach

The reaction of lactonization of olefins with carboxyalkyl radicals and Mn(OAc)3 was carried out under ultrasound irradiation at low temperatures. Good yields of lactones were obtained in short reaction times. In sonochemical conditions, reoxid

Synthesis and chemical transformations of six/six-membered bicyclic nitroso acetals

A synthesis of hitherto unknown bicyclic nitroso acetals possessing two annulated six-membered rings is accomplished. The synthesis comprises formal [3+3] cycloaddition of six-membered cyclic nitronates with donor-acceptor cyclopropanes. Some chemical tra

γ-substituted butanolides from cyclopropane hemimalonates: An expedient synthesis of natural (R)-dodecan-4-olide

Exploration into the reactivity of donor-acceptor cyclopropane hemimalonates has led to the facile synthesis of γ-substituted butanolides. Under microwave irradiation, cyclopropane hemimalonates undergo rapid conversion to butanolides in the presence of i

New dimerization and cascade oligomerization reactions of dimethyl 2-phenylcyclopropan-1,1-dicarboxylate catalyzed by Lewis acids

New routes to transform donor-acceptor cyclopropanes in the presence of Lewis acids have been found. The reaction of dimethyl 2-phenylcyclopropan-1,1- dicarboxylate, a typical representative of this class of compounds, with an equimolar amount of anhydrou

Lewis acid-catalyzed isomerization of 2-arylcyclopropane-1,1- dicarboxylates: A new efficient route to 2-styrylmalonates

A facile efficient approach to the 2-styrylmalonates via the Lewis acid-catalyzed isomerization of 2-arylcyclopropane-1,1-dicarboxylates has been developed. The efficiency of this method was demonstrated for a representative series of such cyclopropanes.

Oxidative addition of dimethyl malonate to styrenes mediated by cerium(IV) ammonium nitrate: Some novel observations

The oxidative addition of dimethyl malonate to ring substituted styrenes leads to the formation of substituted dimethyl (2-oxo-2-phenylethyl) malonate and methyl 2-oxo-5-phenyltetrahydrofuran-3-carboxylate along with small amounts of substituted dimethyl [2-(nitrooxy)-2-phenylethyl] malonate and dimethyl 2-methoxy-2-phenylethyl) malonate. A tentative mechanism which supports the formation of these products is also presented.

Cerium(IV) ammonium nitrate mediated addition of dimethyl malonate to styrene: a remarkable reaction

Cerium(IV) ammonium nitrate mediated addition of dimethyl malonate to styrene afforded the products 3 and 4 (via 7) along with small amounts of 5 and 6.