23000-32-0Relevant articles and documents
A transition-metal-free fast track to flavones and 3-arylcoumarins
Golshani, Mostafa,Khoobi, Mehdi,Jalalimanesh, Nafiseh,Jafarpour, Farnaz,Ariafard, Alireza
supporting information, p. 10676 - 10679 (2017/10/06)
A highly regioselective and transition-metal free one-pot arylation of chromenones with arylboronic acids has been achieved employing K2S2O8. The procedure consists of a sequence of some reactions including an arylation/decarboxylation cascade and proceeds well in aqueous media to afford biologically interesting flavones and 3-arylcoumarins. This method exhibited excellent selectivity and functional group tolerance under mild conditions. The reaction also showed perfect efficacy for the preparation of styryl coumarins.
A complete switch of the directional selectivity in the annulation of 2-hydroxybenzaldehydes with alkynes
Zeng, Huiying,Li, Chao-Jun
supporting information, p. 13862 - 13865 (2015/01/09)
Controlling reaction selectivity is an eternal pursuit for chemists working in chemical synthesis. As part of this endeavor, our group has been exploring the possibility of constructing different natural product skeletons from the same simple starting mat
Palladium-catalyzed decarboxylative cross-coupling reactions: A route for regioselective functionalization of coumarins
Jafarpour, Farnaz,Zarei, Samaneh,Olia, Mina Barzegar Amiri,Jalalimanesh, Nafiseh,Rahiminejadan, Soraya
, p. 2957 - 2964 (2013/06/05)
A straightforward, regioselective, and step-economical ligand-free palladium-catalyzed decarboxylative functionalization of coumarin-3-carboxylic acids is devised. This protocol is compatible with a wide variety of electron-donating and -withdrawing substituents and allows for construction of various biologically important π-electron extended coumarins.