23014-42-8

Upstream product

• 23014-44-0 2-Acetyl-3-dimethylamino-5,5-dimethyl-cyclohex-2-enone 
• 33190-11-3 2-acetyl-5,5-dimethyl-3-methylamino-2-cyclohexen-1-one 
• 23014-46-2 2-Acetyl-3-benzylamino-5,5-dimethyl-cyclohex-2-enone 
• 82681-89-8 2-acetyl-3-isopropylamino-5,5-dimethyl-2-cyclohexen-1-one 
• 177211-20-0 3,6,6-trimethyl-6,7-dihydro-2,1-benzisoxazol-4(5H)-one 
• 3471-13-4 dimedone 
• 21014-79-9 2-acetyl-3-methoxy-5,5-dimethyl-cyclohex-2-enone 
• 37513-99-8 2-acetyldimedone 
• 53173-69-6 3,6,6-trimethyl-6,7-dihydro-1,2-benzisoxazol-4(5H)-one 
• 177211-18-6 (E)-(3,6,6-trimethyl-6,7-dihydro-1,2-benzisoxazol-4(5H)-one oxime) 
• 18809-53-5 2-acetyl-5,5-dimethyl-3-N-pyrrolidylcyclohex-2-en-1-one 
• 25435-67-0 2-acetyl-3-chloro-5,5-dimethyl-2-cyclohexen-1-one 

Downstream Products

• 1332702-66-5 C₁₀H₁₅BF₃NO₂ 

Relevant academic research and scientific papers

Molybdenum hexacarbonyl promoted ring-opening of hydroxyimino isoxazoles: Unexpected pyrazole formation

Fused isoxazoles underwent reductive ring-opening in the presence of molybdenum hexacarbonyl to give the corresponding β-disubstituted compounds. 3,6,6-Trimethyl-6,7-dihydro-1,2-benzisoxazol-4(5H)-one oxime underwent reductive ring-opening in the presence of molybdenum hexacarbonyl to give 3,6,6-trimethyl-6,7-dihydro-1H-indazol-4(5H)-one. A mechanism is proposed.

Photochemical Dealkylation of 2-Acyl-3-alkylamino-5,5-dimethyl-2-cyclohexen-1-ones

The photochemical behavior of a number of 2-acyl-3-alkylamino-5,5-dimethyl-2-cyclohexen-1-ones has been investigated.Irradiation of these systems resulted in δ- hydrogen abstraction by the excited carbonyl oxygen to form a biradical intermediate, which pr