23115-24-4Relevant academic research and scientific papers
Ruthenium-catalyzed dealkenative N-silylation of amines by substituted vinylsilanes
Marciniec, Bogdan,Kostera, Sylwia,Wyrzykiewicz, Bozena,Pawlu, Piotr
, p. 782 - 786 (2014)
The ruthenium hydride complex-catalyzed N-silylation of primary and secondary amines with substituted vinylsilanes, with the general formula R1CHCHSiR′3 (where R1 = H, Ph, n-Bu, Si(OEt)3), leading to the formation of a Si-
Chlorosilane alcoholysis acid removing agent and regeneration method thereof
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Paragraph 0019, (2017/04/28)
The invention discloses a chlorosilane alcoholysis acid removing agent and a regeneration method thereof. The regeneration method is characterized in that at a temperature of -10-130 DEG C, a substituting agent and an acid removing agent are added into a reactor in advance, chlorosilane is gradually added, the liquid phase obtained through filtration separation is subjected to rectification after the alcoholysis reaction is completed so as to obtain a silane finished product and the excessive substitution agent, the excessive substitution agent is recycled, and the acid removing agent obtained through filtration separation is recycled after being regenerated. According to the present invention, the yield of the silane prepared by using the process is more than or equal to 95%, and the recovery rate of the acid removing agent is more than or equal to 95%.
